Volume Expansion: Answers to Homework Questions

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The discussion focuses on the behavior of a mercury thermometer when replaced with alcohol, which has a higher coefficient of volume expansion. Participants express confusion about calculating the temperature readings for the alcohol thermometer at different temperatures without knowing the initial temperature. The relationship between the change in volume for alcohol and mercury is highlighted, emphasizing the need for proper ΔT values. The importance of establishing a baseline height for the alcohol in the thermometer is also mentioned to ensure accurate temperature markings. Accurate calculations depend on understanding these volume changes and the initial conditions of the thermometer.
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Homework Statement



A standard mercury thermometer consists of a hollow glass cylinder, the stem, attached to a bulb filled with mercury. As the temperature of the thermometer changes, the mercury expands (or contracts) and the height of the mercury column in the stem changes. Marks are made on the stem to denote the height of the mercury column at different temperatures such as the freezing point (0∘C) and the boiling point (100∘C) of water. Other temperature markings are interpolated between these two points.

Due to concerns about the toxic properties of mercury, many thermometers are made with other liquids. Consider draining the mercury from the above thermometer and replacing it with another, such as alcohol. Alcohol has a coefficient of volume expansion 5.6 times greater than that of mercury. The amount of alcohol is adjusted such that when placed in ice water, the thermometer accurately records 0∘C. No other changes are made to the thermometer.

1) When the alcohol thermometer is placed in 20∘Cwater, what temperature will the thermometer record?

2)
When the alcohol thermometer is placed in a −10∘C substance, what temperature will the thermometer record?3)If you want to design a thermometer with the same spacing between temperature markings as a mercury thermometer, how must the diameter of the inner hollow cylinder of the stem of the alcohol thermometer compare to that of the mercury thermometer? Assume that the bulb has a much larger volume than the stem.(solved)

The Attempt at a Solution

ΔVA = VAiαΔT

The cylinder has a volume: πr2h

Change in volume of alcohol in a cylinder: ΔVA = πr2h(5.6α)ΔT

Change of volume of mercury in a cylinder: ΔVM = πr2h.α.ΔT

I am experiencing a confusion here. Question states that the thermometer is placed into a water of 20°C. However, nothing was said about the initial temperature. Without this piece of information I cannot utilize ΔT.
 
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You know the reading at 0 degrees C. So 20 would be a good ΔT. You also know that the corresponding ΔVM makes the mercury rise to the 20[sup∘[/sup]C mark.
 
BvU said:
You know the reading at 0 degrees C. So 20 would be a good ΔT. You also know that the corresponding ΔVM makes the mercury rise to the 20[sup∘[/sup]C mark.

I don't...
what is the height of the thermometer at 0 and 20 degree celsius?
 
Give it a name: "0". The makers of the device make a mark and write a zero at that height. Then the Hg is drained and the C2H5OH is filled up to that height on the scale.

[edit] as for the 20 one: that's the real exercise for you to do. It has to be calculated from the difference in ΔV.
 
The book claims the answer is that all the magnitudes are the same because "the gravitational force on the penguin is the same". I'm having trouble understanding this. I thought the buoyant force was equal to the weight of the fluid displaced. Weight depends on mass which depends on density. Therefore, due to the differing densities the buoyant force will be different in each case? Is this incorrect?

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