Thermal Physics Expansion Coefficient Problem

In summary, the conversation discusses the thermal expansion coefficient of liquid mercury and its relationship to temperature. The problem statement asks to estimate the size of the bulb and the inside diameter of the tube for a mercury thermometer to function properly, assuming the thermal expansion of the glass is negligible. The conversation includes equations and a solution to calculate the required diameter based on the initial volume of the bulb, the length of the thermometer, and the change in temperature. The conversation also discusses the assumptions and limitations of the solution.
  • #1
Bashyboy
1,421
5

Homework Statement


When the temperature of liquid mercury increases by one degree Celsius (or one kelvin), its volume increases by one part in 550,000. The fractional increase in volume per unit change in temperature (when the pressure is held fixed) is called the thermal expansion coefficient, [itex]\beta[/itex]:

[itex]\displaystyle \beta \equiv \frac{\Delta V/V}{\Delta T}[/itex]

(where V is volume, T is temperature, and A signifies a change, which in this case should really be infinitesimal if 0 is to be well defined). So for mercury, (3 = 1/550,000 K"1 = 1.81 x 10~4 K_1. (The exact value varies with temperature, but between 0°C and 200° C the variation is less than 1%.)

(a) Get a mercury thermometer, estimate the size of the bulb at the bottom,
and then estimate what the inside diameter of the tube has to be in order for
the thermometer to work as required. Assume that the thermal expansion
of the glass is negligible.

Homework Equations


The Attempt at a Solution



Suppose at the temperature [itex]T_0[/itex] all of the mercury is in the bulb of the thermometer; and suppose the radius of the bulb is [itex]r_0[/itex], from which we can get the volume of the bulb, assuming it to be spherical, and consequently the volume of the mercury (the space it occupies). Suppose, by some external means, the temperature of the mercury increases from [itex]T_0[/itex] to [itex]T[/itex], [itex]\Delta T = T - T_0[/itex]. Due to the fact that things expand when their temperature changes, the mercury will begin to diffuse upwards into the cylinder portion of the thermometer, but some will remain in the bulb.

Now, suppose that when the mercury reaches the temperature [itex]T[/itex], the mercury occupies all of the volume that the thermometer can afford. So, when [itex]T_0[/itex], [itex]V_0 = \frac{4}{3} \pi r^3_0[/itex]; and when the temperature changes to [itex]T[/itex], [itex]V = \underbrace{V_0}_{Initial~volume} + \underbrace{l_0 \pi r_1^2}_{Volume~ due~ to~ expansion}[/itex], where [itex]l_0[/itex] is the length of the thermometer, and [itex]r_1[/itex] is the radius of the cylinder, the variable of which we are solving for.

The change in volume: [itex]\Delta V = (V_0 + l_0 \pi r^2_1) - V_0 = l_0 \pi r^2_1[/itex]

Rearranging the thermal expansion coefficient, and substituting,

[itex]\Delta V = \beta V_0 (T-T_0)[/itex]

[itex]l_0 \pi r^2_1 = \beta V_0 (T-T_0) [/itex]

[itex]\displaystyle r_1 = \sqrt{\frac{\beta V_0 (T-T_0)}{l_0 \pi}}[/itex]

At this point I would make assumptions regarding the values of the radius of the bulb and the length of the thermometer, as per the directions of the problem statement

If I understand this question properly, then if one was to build a thermometer, such that at temperature [itex]T_0[/itex], the mercury occupied the volume of the bulb. And because of these conditions, these would determine what radius of the of the cylinder portion of the thermometer has to be. These seems to make some sense, but I would appreciate if someone could logically explain these, to clarify this issue. Another thing I am dealing with is, notice the formula that I derived: the radius of the cylinder does not depend on the [itex]T[/itex] or [itex]T_0[/itex] individually, but on the change in temperature. Why is that so, why does it not depend on the beginning and ending temperature, aside from it being mathematically true? I am having a little difficulty grasping that.
 
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  • #2
Bashyboy said:

Homework Statement


When the temperature of liquid mercury increases by one degree Celsius (or one kelvin), its volume increases by one part in 550,000. The fractional increase in volume per unit change in temperature (when the pressure is held fixed) is called the thermal expansion coefficient, [itex]\beta[/itex]:

[itex]\displaystyle \beta \equiv \frac{\Delta V/V}{\Delta T}[/itex]

(where V is volume, T is temperature, and A signifies a change, which in this case should really be infinitesimal if 0 is to be well defined). So for mercury, (3 = 1/550,000 K"1 = 1.81 x 10~4 K_1. (The exact value varies with temperature, but between 0°C and 200° C the variation is less than 1%.)

(a) Get a mercury thermometer, estimate the size of the bulb at the bottom,
and then estimate what the inside diameter of the tube has to be in order for
the thermometer to work as required. Assume that the thermal expansion
of the glass is negligible.


Homework Equations





The Attempt at a Solution



Suppose at the temperature [itex]T_0[/itex] all of the mercury is in the bulb of the thermometer; and suppose the radius of the bulb is [itex]r_0[/itex], from which we can get the volume of the bulb, assuming it to be spherical, and consequently the volume of the mercury (the space it occupies). Suppose, by some external means, the temperature of the mercury increases from [itex]T_0[/itex] to [itex]T[/itex], [itex]\Delta T = T - T_0[/itex]. Due to the fact that things expand when their temperature changes, the mercury will begin to diffuse upwards into the cylinder portion of the thermometer, but some will remain in the bulb.

Now, suppose that when the mercury reaches the temperature [itex]T[/itex], the mercury occupies all of the volume that the thermometer can afford. So, when [itex]T_0[/itex], [itex]V_0 = \frac{4}{3} \pi r^3_0[/itex]; and when the temperature changes to [itex]T[/itex], [itex]V = \underbrace{V_0}_{Initial~volume} + \underbrace{l_0 \pi r_1^2}_{Volume~ due~ to~ expansion}[/itex], where [itex]l_0[/itex] is the length of the thermometer, and [itex]r_1[/itex] is the radius of the cylinder, the variable of which we are solving for.

The change in volume: [itex]\Delta V = (V_0 + l_0 \pi r^2_1) - V_0 = l_0 \pi r^2_1[/itex]

Rearranging the thermal expansion coefficient, and substituting,

[itex]\Delta V = \beta V_0 (T-T_0)[/itex]

[itex]l_0 \pi r^2_1 = \beta V_0 (T-T_0) [/itex]

[itex]\displaystyle r_1 = \sqrt{\frac{\beta V_0 (T-T_0)}{l_0 \pi}}[/itex]

At this point I would make assumptions regarding the values of the radius of the bulb and the length of the thermometer, as per the directions of the problem statement

If I understand this question properly, then if one was to build a thermometer, such that at temperature [itex]T_0[/itex], the mercury occupied the volume of the bulb. And because of these conditions, these would determine what radius of the of the cylinder portion of the thermometer has to be. These seems to make some sense, but I would appreciate if someone could logically explain these, to clarify this issue. Another thing I am dealing with is, notice the formula that I derived: the radius of the cylinder does not depend on the [itex]T[/itex] or [itex]T_0[/itex] individually, but on the change in temperature. Why is that so, why does it not depend on the beginning and ending temperature, aside from it being mathematically true? I am having a little difficulty grasping that.
In reality, it does depend on the beginning and end temperatures, but, as an approximation, you are linearizing with respect to some average temperature, and even although the volume depends on the temperature, the change in volume is a linear function of the temperature change (to an excellent approximation) over the range of temperatures.

I don't understand what else you are asking. Basically, you are trying to get an understanding of the steps involved in designing a thermometer. You start out by choosing a convenient length for the tube over the temperature range of interest. You don't want the thermometer to be 10 ft long, and you don't want it to be 1" long. So you choose something like a foot, maybe. You also choose a convenient size for the reservoir. You've seen thermometers, so you have some idea what this might be. You probably want to minimize the amount of mercury you use for environmental reasons. You then choose a radius so that the mercury in the tube goes from the initial temperature at the bottom to the final temperature at the top. After you're done with this, you then play around with the dimensions a little more, until they satisfy your comfort.

Chet
 
  • #3
Your last result for r1 is excellent. Your intended next step too. As you see, for a given r1 and V0 the value (T-T0)/L0 is determined. So raise of mercury level per degree is fixed. Part of the exercise was to 'get a mercury thermometer'. The idea is to give you a feeling of how very small the inside diameter of the tube has to be. Especially for e.g. an old-fashioned fever thermometer (full scale around 0.1 m for 5 degrees C).

Since the OP is in decent units, stick to meters would be my advice...
 
  • #4
I have another question. Suppose we were to implement the conditions I set-forth in my first post, and find the radius that corresponded to having the mercury only reside in the bulb at T = 0 deg C, and then occupying the entire volume of the thermometer at T = 100 deg C. Suppose that value were r0. Now, if I were to build a thermometer with the given specifications, except make the radius of the cylinder such at it's actually greater than r0, when the mercury reaches 100 deg C, it would not occupy the entire thermometer, right? The radius r0 is fine-tuned?
 
  • #5
This sounds like a practical question. Don't know much about making thermometers. I suppose tolerances in r0 are so tight that calibrating the scale only once is good enough for a batch of glass tubes. There will be no fine tuning: narrowing is difficult and widening even worse. The instrument would be too expensive.
But you are right about not occupying the whole thing.
 
  • #6
Bashyboy said:
I have another question. Suppose we were to implement the conditions I set-forth in my first post, and find the radius that corresponded to having the mercury only reside in the bulb at T = 0 deg C, and then occupying the entire volume of the thermometer at T = 100 deg C. Suppose that value were r0. Now, if I were to build a thermometer with the given specifications, except make the radius of the cylinder such at it's actually greater than r0, when the mercury reaches 100 deg C, it would not occupy the entire thermometer, right? The radius r0 is fine-tuned?
Why don't you just try to do an actual design and see what you get? It's occupying more of your speculating about such questions than it would to actually try some design iterations and see what happens.
 
  • #7
And how would I design one, with a computer?
 
  • #8
No, by applying your last expression for r1. Design an old fashioned fever thermometer (10 cm delta height for a range of 36-41 degrees C) and then a school thermometer (30 cm scale for -30 to +120 C).
 
  • #9
Bashyboy said:
And how would I design one, with a computer?
I would use a slide rule, but you can use a calculator.
 
  • #10
I am not familiar with the slide rule. What is it?
 
  • #11
Bashyboy said:
I am not familiar with the slide rule. What is it?
It's a wooden mechanical device that we used to use to do arithmetic before they had calculators.
 
  • #12
Behold! The slide rule (or slip stick as it is sometimes known):

http://en.wikipedia.org/wiki/Slide_rule

The circle of my life is now complete. I've gone from slide rules, desktop calculators, and mechanical adding machines to electronic calculators and microcomputers to someone asking, "What's a slide rule?"
 
  • #13
Come on folks, this is serious business. Bashy, get to work and show us how you calculate r1 for the two thermometers I proposed. I'll postpone my next post until you've posted that. ;-)
 
  • #14

1. What is the thermal expansion coefficient?

The thermal expansion coefficient, also known as the coefficient of thermal expansion, is a measure of the change in size or volume of a material with temperature. It is typically represented by the Greek letter alpha (α) and is expressed in units of length per degree Celsius (or Kelvin).

2. How is the thermal expansion coefficient calculated?

The thermal expansion coefficient can be calculated by dividing the change in length or volume of a material by its original length or volume, and then dividing that value by the change in temperature. This value is typically reported in units of 1/°C or 1/°K.

3. Why is the thermal expansion coefficient important?

The thermal expansion coefficient is important because it helps us understand how materials will behave when exposed to changes in temperature. This is useful in many practical applications, such as designing structures that can withstand temperature changes without breaking or warping.

4. How does the thermal expansion coefficient vary between materials?

The thermal expansion coefficient can vary significantly between different materials. Generally, materials with stronger bonds between atoms, such as metals, have lower thermal expansion coefficients, while materials with weaker bonds, such as plastics, have higher coefficients. Additionally, the thermal expansion coefficient can also vary depending on the temperature range being considered.

5. How does the thermal expansion coefficient affect everyday objects?

The thermal expansion coefficient can affect everyday objects in various ways. For example, it can cause gaps or cracks in concrete structures when the temperature changes, or it can cause the lids of jars to become difficult to open when they are heated. Understanding the thermal expansion coefficient of materials is crucial in manufacturing and designing products that will be exposed to temperature changes.

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