Volume work, absolute and relative pressure confusion

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kandelabr
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hello.

i can't figure out where I'm wrong. this is the problem:

we have a cylinder, closed with a piston. the absolute pressure inside the cylinder is p0, atmospheric pressure is patm. the air inside expands isothermally to some (specific) volume vend.
i derived the equation for isothermal work directly from this one: dW = F(s)ds.

here it is (sorry for handwriting... uses less time :eek: (will learn TeX one day... :smile:)):
isotherm.jpg


the final equation seems just fine, but you've probably noticed the big fat asterisk. here's why:
p0 is absolute pressure and it exerts F(s0) on the piston. but there is also patm, which does negative work equal to patm * A * (send - s0). this fact hasn't been taken into account anywhere.

where am i wrong (the thermodynamics probably isn't wrong, right? :) )
 
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What you are calculating is the work done by the gas on the piston, not the net work done on the piston. The gas is not subjected to atmospheric pressure--it's contained in the cylinder.
 
oh, i get it.
but if now i want to know how much work i can get from this piston, i need to include atmospheric pressure.