What are some nonreactive electrolyte solutions?

  • Thread starter Thread starter Xtensity
  • Start date Start date
Click For Summary
SUMMARY

The discussion focuses on identifying nonreactive electrolyte solutions suitable for electrochemical hydrogenation of alcohols. The user seeks alternatives to basic sulfuric acid, which would react violently with the alcohol. Suggested options include sodium sulfate and other inert salts that do not participate in oxidation or reduction reactions during the process. The goal is to maintain a clean electrochemical environment while effectively conducting the reaction.

PREREQUISITES
  • Understanding of electrochemical reduction processes
  • Familiarity with catholyte solutions and their properties
  • Knowledge of inert salts and their roles in electrochemical cells
  • Basic principles of acid-base extraction techniques
NEXT STEPS
  • Research the properties of sodium sulfate as a catholyte in electrochemical reactions
  • Explore other inert salts suitable for use in electrochemical cells
  • Learn about electrochemical hydrogenation techniques and best practices
  • Investigate methods for acid-base extraction following electrochemical reactions
USEFUL FOR

Chemists, electrochemists, and researchers involved in organic synthesis and electrochemical processes will benefit from this discussion.

Xtensity
Messages
103
Reaction score
0
I have an alcohol that I need to hydrogenate/reduce and I would like to do it electrochemically. The catholyte solutions I am used to using are basic sulfuric acid, but that would not work in this case as it would cause a violent reaction with the alcohol. The alcohol could be reduced with an acid but I would prefer to do it electrochemically as it is much cleaner. I need some sort of electrolyte, either soluble in alcohol or water, that can act as a conductor in this cell, but not react with the alcohol that I am reducing. Following the reduction is the usual workout with an acid-base extraction so there's no worry about difficulty in removing the elctrolyte.

Any ideas?
 
Chemistry news on Phys.org
Sodium sulfate? Basically any inert salt that won't easily get oxidized nor reduced.
 

Similar threads

Replies
5
Views
3K
  • · Replies 6 ·
Replies
6
Views
2K
Replies
1
Views
2K
  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 8 ·
Replies
8
Views
3K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
1
Views
3K
Replies
5
Views
1K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 19 ·
Replies
19
Views
8K