What causes metal-insulator transition in rare earth nickelate compounds?

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Discussion Overview

The discussion focuses on the metal-insulator transition in rare earth nickelate compounds, particularly the mechanisms behind this transition when the material is heated to certain temperatures. The scope includes theoretical aspects and potential historical context regarding the understanding of these materials.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • Ngom inquires about the mechanism that allows rare earth nickelates to transition from an insulating state to a metallic state upon heating.
  • One participant suggests that the transition in some perovskite nickelates (RNiO3) may have been previously associated with a weak Jahn-Teller distortion, although this understanding may be outdated.
  • Another participant expresses a willingness to find more recent research papers on the topic but notes that the initial information provided is limited.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the mechanisms behind the metal-insulator transition, and multiple views regarding the historical understanding of the phenomenon remain present.

Contextual Notes

The discussion lacks detailed recent studies or comprehensive explanations of the underlying physics, and assumptions regarding the Jahn-Teller distortion are not fully explored.

Ngom
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Dear everydody can you please help me to understand how can by heating your sample they jumb from Insulater state to an metal state when we rich to a certain value of temperature for exemple the Rare Earth Nickelate compounds.

Best regard
Ngom
 
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If you are referring to the perovskite nickelates (RNiO3), I can tell you that about 10 years ago, it was believed that (I think in at least some of the compounds) the transition was associated with a weak Jahn-Teller distortion. I've not followed up since then.
 
Thank for the time that you use to reply to me if you have more information please let me know.
 
Unfortunately, that's the crux of what I recall.

I think I might be able to dig up some papers on this though...but then, that's probably something that you can do as well as me.
 

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