Graeme M said:
Though here I am not sure why it talks of wavelength rather than frequency
I went into that. It's just historical and it is now the convention. There would be no point in changing, at this stage.
Graeme M said:
there seems to me to be a fair amount of potential latitude in the exact numbers of cone cells stimulated.
Yes, I'm sure there is. Our actual memory for colours is pretty poor (which is why we have to take the curtains into the shop when choosing the wallpaper and one's wife would not allow you to go out and choose a top for her birthday, without taking the skirt with you). But we can distinguish between the 'millions of colours' that your TV monitor can give you, in some really critical material (large areas of nearly the same colour). The 'experiment' you describe would not be a good one because it would be illuminating the whole retina so there would be no reference with which the eye could calibrate itself. I also previously mentioned the poor colour memory in a darkened cinema, compared with viewing TV in the home.
Graeme M said:
but does it follow that every human retina responds to that in exactly the same proportion?
This has also been mentioned before. Is it not well known that the colour sense varies a lot from person to person? (And animal to animal) What is far more important is the discrimination between adjacent areas - revealing patterns and shapes with predators and prey are against a similar coloured background and the slight blush of embarrassment or pleasure on another person's face. We are very very good at that.
Graeme M said:
We still have to agree on what spectral yellow is before we can assign a wavelength to THAT colour.
I can't imagine a 'Scientist' going to a lot of trouble to name the colour of a spectral line in an experiment - except in very broad terms. The whole point of assigning a wavelength to a spectral line is to make it possible to refer to it with precision. Otoh, an artist, who would never be dealing with spectral lines (there may be exceptions to that statement but it wouldn't involve pigments) will be using an entirely different way of referring to the colours (see the 'Colour Wheel" system) which doesn't refer to wavelength at all. If you look at the CIE diagram, it is surely pretty obvious that the majority of colours in that colour space do not lie on the spectral arch, over the top.
There is no disagreement between the Colour and Wavlength descriptions. They are just appropriate in different contexts. The only thing is to avoid using them for the same thing.
P.S.
Graeme M said:
if we want to create spectral yellow
. . .we wouldn't use a reflective surface or a filter. We would use a light emitter - probably a sodium discharge lamp. Nothing else would give a totally pure match. (Google colour synthesis in TV and read about the principles behind it). PF can only do so much.