Attached is a drawing showing, for example, NMOS and PMOS speed with FF, SS, FS, amd SF corners. Yes, temperature is typically on top of this. Digital logic tends to slow down as it gets hotter, so a (S,S,Hot) corner will typically be slower than a (S,S,Room) corner. However, different circuits respond differently, so you usually have to run all process and temperature corners to determine which is the slowest. Also, people tend to think that the faster corners are always better, but some circuits can be too fast at the fast corners (if your circuit has race conditions for instance). Analog circuits tend to have problems at FS and SF corners where device matching can be compromised.