What is the Crystal Structure of Aluminum and its Bonding Patterns?

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SUMMARY

The discussion focuses on the crystal structure of pure aluminum, specifically its face-centered cubic (FCC) arrangement. Participants clarify that the FCC lattice consists of an ABCABC stacking pattern, which differs from simpler ABAB patterns. The bonding in metals like aluminum is not represented by distinct shapes such as tetrahedral or octahedral, as metals typically exhibit metallic bonding without defined angles. The conversation emphasizes the importance of understanding the stacking order in FCC structures for accurate modeling.

PREREQUISITES
  • Understanding of face-centered cubic (FCC) crystal structures
  • Knowledge of metallic bonding and its characteristics
  • Familiarity with atomic stacking patterns in crystallography
  • Basic skills in model-making for visual representation
NEXT STEPS
  • Research the properties of face-centered cubic (FCC) lattices in metals
  • Study the concept of metallic bonding and its implications
  • Learn about close-packed crystal structures and their stacking sequences
  • Explore modeling techniques for representing crystal structures accurately
USEFUL FOR

This discussion is beneficial for students in materials science, chemists studying crystallography, and hobbyists interested in model-making of metal structures.

LABQT
For my project, I am creating a pure aluminum model with styro foam balls and toothpicks. I know this structure is a "face-centered cubic". However, I don't know the bonding angles and what kind of bonding shape (tetrahedral, octahedral ...), I need the information for the write-up. Can someone help please.
 
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Er... being a metal, I wouldn't think pure aluminium would really form any distinct bonds that you can represent. Most models of metal crystals are simply layers of balls glued onto each other.

To visualise a face centred cubic structure, picture a cube with eight aluminium particles, one on each vertex. At the centre of each face, there is an additional particle. Repeat pattern many times, et viola.

eg.

Code:
Layer 1:

O   O   O
  O   O
O   O   O
  O   O
O   O   O

Layer  2:

  O   O
O   O   O
  O   O
O   O   O
  O   O

Layer 3:


O   O   O
  O   O
O   O   O
  O   O
O   O   O

Don't trust my crappy diagram so much though.
 
Last edited:
Thanks for the reply. Now I understand.
 
I think the third layer is wrong.
 
adianadiadi said:
I think the third layer is wrong.

The third layer is identical to the first layer. And the fourth would be identical to the second and so on. It is basically the way in which the atoms stack together the best. If all the layers were identical there would be too much empty space between atoms.
 
But In aluminium, there is FCC lattice. That means, the third layer must be different also. It has ABCABC-----pattern and not ABAB_____ pattern
 
adianadiadi said:
But In aluminium, there is FCC lattice. That means, the third layer must be different also. It has ABCABC-----pattern and not ABAB_____ pattern

This is correct if one is drawing the close-packed {111} planes. But FZ+ drew the {100} planes correctly; every other {100} plane is identical.
 

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