What is the Crystal Structure of Aluminum and its Bonding Patterns?

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Discussion Overview

The discussion revolves around the crystal structure of aluminum, specifically its face-centered cubic (FCC) arrangement and the associated bonding patterns. Participants explore the representation of this structure in a model and clarify the stacking sequence of layers in the FCC lattice.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant seeks information on bonding angles and shapes for a model of pure aluminum, identifying its structure as face-centered cubic.
  • Another participant suggests that pure aluminum, being a metal, may not form distinct bonds suitable for representation in a model.
  • There is a discussion about the visualization of the FCC structure, with one participant providing a diagrammatic representation of layers.
  • Multiple participants challenge the accuracy of the layer representation, with one asserting that the third layer should be identical to the first layer, while another insists on the ABCABC stacking pattern characteristic of FCC lattices.
  • Clarifications are made regarding the correct representation of {100} and {111} planes in the FCC structure, indicating that every other {100} plane is identical.

Areas of Agreement / Disagreement

Participants express differing views on the correct representation of the stacking sequence in the FCC lattice, with no consensus reached on the accuracy of the proposed layer diagrams.

Contextual Notes

There are unresolved assumptions regarding the representation of atomic bonding in metals and the specific details of layer stacking in FCC structures.

LABQT
For my project, I am creating a pure aluminum model with styro foam balls and toothpicks. I know this structure is a "face-centered cubic". However, I don't know the bonding angles and what kind of bonding shape (tetrahedral, octahedral ...), I need the information for the write-up. Can someone help please.
 
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Er... being a metal, I wouldn't think pure aluminium would really form any distinct bonds that you can represent. Most models of metal crystals are simply layers of balls glued onto each other.

To visualise a face centred cubic structure, picture a cube with eight aluminium particles, one on each vertex. At the centre of each face, there is an additional particle. Repeat pattern many times, et viola.

eg.

Code:
Layer 1:

O   O   O
  O   O
O   O   O
  O   O
O   O   O

Layer  2:

  O   O
O   O   O
  O   O
O   O   O
  O   O

Layer 3:


O   O   O
  O   O
O   O   O
  O   O
O   O   O

Don't trust my crappy diagram so much though.
 
Last edited:
Thanks for the reply. Now I understand.
 
I think the third layer is wrong.
 
adianadiadi said:
I think the third layer is wrong.

The third layer is identical to the first layer. And the fourth would be identical to the second and so on. It is basically the way in which the atoms stack together the best. If all the layers were identical there would be too much empty space between atoms.
 
But In aluminium, there is FCC lattice. That means, the third layer must be different also. It has ABCABC-----pattern and not ABAB_____ pattern
 
adianadiadi said:
But In aluminium, there is FCC lattice. That means, the third layer must be different also. It has ABCABC-----pattern and not ABAB_____ pattern

This is correct if one is drawing the close-packed {111} planes. But FZ+ drew the {100} planes correctly; every other {100} plane is identical.
 

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