What is the energy of the following state (quantum square)?

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SUMMARY

The energy of an STM tunneling electron in a quantum square model, analogous to a "particle in a 2-D box," can be calculated using the formula E = n^2 * h^2 / (8*m*L^2). For this specific case, the dimensions are Lx = 2.02e-10 m and Ly = 2.77e-10 m, with Planck's constant h = 6.626e-34 J*s and the effective mass of the electron m = 3.461e-31 kg. The user seeks clarification on the values of quantum numbers nx and ny, questioning whether the black dots in the provided diagram represent nodes or actual n values.

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  • Understanding of quantum mechanics principles, specifically the particle in a box model.
  • Familiarity with STM (Scanning Tunneling Microscopy) and its applications.
  • Knowledge of fundamental constants such as Planck's constant and electron mass.
  • Ability to perform calculations involving quantum energy levels.
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Homework Statement


[/B]
What is the energy of an STM tunneling electron in the following state? This "quantum square" model can be seen as a "particle in a 2-D box" problem.
<Refer to the picture below>
The protrusions are Fe atoms and the surface is Cu(111).
Given that the radius of an Fe atom is 126 pm (1.26e-10 m), I've calculated that the shorter side, Lx, equals 2.02e-10 m. Likewise, the longer side, Ly equals 2.77e-10 m.

Lx = 2.02e-10 m
Ly = 2.77e-10 m
h = Planck's constant = 6.626e-34 J*s
m = effective mass of an electron in this scenario = 0.38me = 0.38 * 9.109e-31 kg = 3.461e-31 kg

Jy6Ory4.png

Homework Equations



E = n^2 * h^2 / (8*m*L^2)
Ex, y = nx^2 * h^2 / (8 * m * Lx^2) + ny^2 * h^2 / (8 * m * Ly^2)

The Attempt at a Solution


[/B]
All I need to know are the constants, nx and ny, the rest of the problem would just be a plug and chug. Although, I don't think the number of Fe atoms represent the n constants. I believe that the number of nodes + 1 would give me the values I need, but I'm not quite sure what in this picture represents the nodes. Do the black dots in the square represent the nodes? Or do they represent the actual n values? If they represented the n values, would nx = 3 and would ny = 4?
 
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Thanks for the post! Sorry you aren't generating responses at the moment. Do you have any further information, come to any new conclusions or is it possible to reword the post?
 

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