What is the Molar Solubility of BaF2 in Water and NaF Solution?

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SUMMARY

The molar solubility of barium fluoride (BaF2) in water at 25 degrees Celsius is calculated using its solubility product constant (Ksp), which is 1.0 x 10^-16. The dissolution of BaF2 can be represented by the equation BaF2 (s) ⇌ Ba2+ (aq) + 2F- (aq). In pure water, the molar solubility is determined to be approximately 1.0 x 10^-8 M. When BaF2 is dissolved in a 0.15 M sodium fluoride (NaF) solution, the presence of F- ions decreases the molar solubility of BaF2 due to the common ion effect, resulting in a significantly lower solubility compared to that in pure water.

PREREQUISITES
  • Understanding of solubility product constant (Ksp)
  • Knowledge of chemical equilibrium principles
  • Familiarity with the common ion effect
  • Basic skills in stoichiometry and concentration calculations
NEXT STEPS
  • Study the common ion effect in detail
  • Learn how to calculate molar solubility using Ksp values
  • Explore the concept of chemical equilibrium in aqueous solutions
  • Investigate the solubility of other salts in the presence of common ions
USEFUL FOR

Chemistry students, educators, and professionals involved in analytical chemistry or environmental science who are interested in solubility principles and their applications in real-world scenarios.

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Homework Statement



A.) Calculate the molar solubility of barium fluoride BAF2 in water at 25 degrees Celsius. The solubility product constant for BaF2 at this temperature is 1.0 x 10^-16

B.) What is the molar solubility of BaF2 in 0.15 M NaF at 25 degrees Celsius? Compare the solubility in this case with that of BaF2 in pure water.

Homework Equations



A + B --> C + D

Ksp = [D][C] / [A]

The Attempt at a Solution



No clue...
 
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What is exact formula for Ksp of BaF2? How are the concentrations of F- and Ba2+ related? (hint: take a look at the compound formula).

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