What is the Quantization Scheme in Frohlich's Electron-Phonon Interaction Paper?

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Discussion Overview

The discussion revolves around the quantization scheme presented in Frohlich's paper on electron-phonon interactions, specifically focusing on the notation and formulation of the Hamiltonian involving the complex B field. Participants are trying to clarify the roles of various symbols and the structure of the equations used in the paper.

Discussion Character

  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant expresses confusion over the notation used in the quantization of the B field, particularly the use of w and W, and suggests that a creation operator part may be missing.
  • Several participants question the placement of the wavevector w in the quantization expression and whether it should be included inside the summation.
  • There is a discussion about the relationship between the vectors W and w, with some participants asserting that w is the magnitude of W, while others seek clarification on the definitions of the symbols used.
  • One participant proposes an alternative expression for the B field, suggesting that it should be written in a different form to make sense mathematically.
  • Another participant points out that the expressions in the paper should be interpreted in Fourier space, indicating a potential misunderstanding of the context.
  • There is a mention of the need to derive specific equations from the proposed expressions, highlighting the complexity of the mathematical relationships involved.
  • One participant raises a concern about the dependency of W on r, questioning the consistency of the notation used in the Hamiltonian formulation.

Areas of Agreement / Disagreement

Participants generally do not reach a consensus on the interpretation of the quantization scheme and the notation used in Frohlich's paper. Multiple competing views remain regarding the placement of symbols and the mathematical formulation of the B field.

Contextual Notes

Limitations include unresolved definitions of symbols, unclear relationships between variables, and potential misunderstandings of the mathematical context in which the expressions are presented.

kau
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I am reading Frohlic's paper on electron-phonon interaction.
Frohlic.http://rspa.royalsocietypublishing.org/content/royprsa/215/1122/291.full.pdf

Here author has introduced the quantization for complex B field in this paper and claimed to have arrived at the diagonalized form of the hamiltonian. I didn't get the quantization part .I think there is some notational problem. He used w to denote wavevectors and at the sametime in the quantization W sits infront of it.. $$ \vec{B}=\frac{\vec{W}}{w}(2h/2\pi wnvs')^{1/2}\sum_{w} b_{w} e^{iw.r}$$ I think there also should be a creation operartor part as well and that's the reason we will get the kind of term author have claimed to get (only then we need to impose the commutation relation,if there is only this much in B then probably I don't need to impose that at all)..most likely I am missing something here..can anyone help me with it..

thanks.Edit: I have hamiltonian $$H= \int |{div\vec{B}}|^{2}nMs'.\, d^{3}r $$

Now We want to quantize it.
So Author have introduced following scheme $$ \vec{B}=\frac{\vec{W}}{w}(2h/2\pi wnvs')^{1/2}\sum_{w} b_{w} e^{iw.r}$$ Using this and writing the integration in the following form
$$ H=\int(div\vec{B}^{*}div\vec{B}+div\vec{B}div(\vec{B}^{*}) (nMs'/2).\, d^{3}r $$

and then substituting the B we get the following

$$ H=\sum \frac{hs'(\vec{W}.\vec{w})^{2}}{2w^{3}}[b_{w}^{\dagger}b_{w}+b_{w}b_{w}^{\dagger}]$$

Here w is the magnitude of $\vec{W}$... I need the following

$$ H=\sum_{w} \frac{hs'w}{2}[b_{w}^{\dagger}b_{w}+b_{w}b_{w}^{\dagger}]$$
First thing is how someone can decompose
$$ \vec{B}=\frac{\vec{W}}{w}(2h/2\pi wnvs')^{1/2}\sum_{w} b_{w} e^{iw.r}$$?? Why $$\vec{w}$$ should sit outside?
 
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Is there anyone who can give some suggestion on this?
 
If w is the magnitude of ##\vec{W}##, then what is ##\vec{w}##. I don't have the article, so maybe you can explain the meaning of all the symbols.
 
DrDu said:
If w is the magnitude of ##\vec{W}##, then what is ##\vec{w}##. I don't have the article, so maybe you can explain the meaning of all the symbols.
As far as I can understand w is the magnitude of ##\vec{W}## ...and I think it should sit inside the sum...then it would look like usual plane wave decomposition ...but the way it's written here is not clear to me.. i have attached the file..thanks.
 

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kau said:
As far as I can understand w is the magnitude of ##\vec{W}## .
Yes, that's ok. As far as I can see, only ##\mathbf{w}## and w appear in the paper by Froehlich. This still leaves the question what you mean with ##\vec{W}##, ##\vec{w}## and w.
 
DrDu said:
Yes, that's ok. As far as I can see, only ##\mathbf{w}## and w appear in the paper by Froehlich. This still leaves the question what you mean with ##\vec{W}##, ##\vec{w}## and w.
The expression I have written for the quantization of ##\vec{B}## is the same as written in the paper. I copied it from there... The capital ##\vec{W}## sitting in front of the sum over w s is not clear to me..$$ \vec{B}=\frac{\vec{W}}{w}(2h/2\pi wnvs')^{1/2}\sum_{w} b_{w} e^{iw.r}$$.I am trying to understand how someone can write something in that form.
 
I suppose you are right. The relations 2.3 and 2.4 should be formulated in Fourier space.
 
kau said:
The expression I have written for the quantization of ##\vec{B}## is the same as written in the paper. I copied it from there... The capital ##\vec{W}## sitting in front of the sum over w s is not clear to me..$$ \vec{B}=\frac{\vec{W}}{w}(2h/2\pi wnvs')^{1/2}\sum_{w} b_{w} e^{iw.r}$$.I am trying to understand how someone can write something in that form.
What is wrong in writing this?
<br /> \vec{B} = \frac{\vec{k}}{|\vec{k}|} \ N \sum_{\vec{k}} b(\vec{k}) \ e^{i \vec{k} \cdot \vec{r} }<br />
 
samalkhaiat said:
What is wrong in writing this?
<br /> \vec{B} = \frac{\vec{k}}{|\vec{k}|} \ N \sum_{\vec{k}} b(\vec{k}) \ e^{i \vec{k} \cdot \vec{r} }<br />
The question is how the k vector outside the sum is related to the k vector inside the sum. Admittedly, the expression makes no sense as it stands. I suppose Froehlich had something like this in mind:
<br /> \vec{B} = \ \ N \sum_{\vec{k}}\frac{\vec{k}}{\omega}b(\vec{k}) \ e^{i \vec{k} \cdot \vec{r} }<br />
You also have to read carefully: the denominator is ##\omega##, which is constant, and not the absolute value of ##\vec{k}##.
 
  • #10
DrDu said:
The question is how the k vector outside the sum is related to the k vector inside the sum.
Summation label is a dummy index.
Admittedly, the expression makes no sense as it stands. I suppose Froehlich had something like this in mind:
<br /> \vec{B} = \ \ N \sum_{\vec{k}}\frac{\vec{k}}{\omega}b(\vec{k}) \ e^{i \vec{k} \cdot \vec{r} }<br />
Since you seem to know what Froehlich had in mind, can you use this expression of yours to derive equation (2.5) of Froehlich?
You also have to read carefully:
I didn’t read it, let alone “read carefully”.
the denominator is ##\omega##, which is constant, and not the absolute value of ##\vec{k}##.
Can you tell me what is your dispersion relation here?
Finally, for your information, I do not post in this part of PF. I just responded to a PM from Kau.
 
  • #11
kau said:
The expression I have written for the quantization of ##\vec{B}## is the same as written in the paper. I copied it from there... The capital ##\vec{W}## sitting in front of the sum over w s is not clear to me..$$ \vec{B}=\frac{\vec{W}}{w}(2h/2\pi wnvs')^{1/2}\sum_{w} b_{w} e^{iw.r}$$.I am trying to understand how someone can write something in that form.

1) \vec{W}= \pi \vec{n} / V^{1/3}, \vec{n}=(n_{1},n_{2},n_{3}), n_{i}= 0, \pm 1 , \pm 2, \cdots is the wave vector.
2) W = |\vec{W}| is the wave number. This is clear from (2.5) H = \sum_{\vec{W}} \hbar W s \ b^{*}_{\vec{W}} \ b_{\vec{W}} . For this to have unit of energy, Ws must be an angular frequency \omega. Since s is the speed of sound, W has to be the wave number |\vec{W}|.
3) Since the field \vec{B} point in the same direction of the wave vector \vec{W}, we can write \vec{B} = \frac{\vec{W}}{W} B(\vec{r}), and hence \vec{\nabla} \cdot \vec{B} = \frac{1}{W} \vec{W} \cdot \vec{\nabla} B(\vec{r}) .
4) The summation labels are dummy indices \sum_{\vec{P}} = \sum_{\vec{Q}} = \cdots .
5) Write
B(\vec{r}) = \sum_{\vec{Q}} N \ b_{\vec{Q}} \ e^{ i \vec{Q}\cdot \vec{r}} .
Then
\vec{\nabla}B = \sum_{\vec{Q}} N \ ( i \vec{Q}) \ b_{\vec{Q}} \ e^{ i \vec{Q}\cdot \vec{r}}.
So,
\vec{\nabla} \cdot \vec{B} = \sum_{\vec{Q}} \frac{N}{W} \left(i \vec{W} \cdot \vec{Q} \right) \ b_{\vec{Q}} \ e^{ i \vec{Q}\cdot \vec{r}} , and
(\vec{\nabla} \cdot \vec{B})^{*} = \sum_{\vec{P}} \frac{N}{W} \left(-i \vec{W} \cdot \vec{P} \right) \ b^{*}_{\vec{P}} \ e^{ -i \vec{P}\cdot \vec{r}} .
6)
<br /> \begin{align*}<br /> \int dV |\vec{\nabla}\cdot \vec{B}|^{2} &amp;= \sum_{\vec{Q},\vec{P}} \frac{N^{2}}{W^{2}} \ (\vec{W}\cdot \vec{Q}) \ (\vec{W}\cdot \vec{P}) \ b_{\vec{Q}} b^{*}_{\vec{P}} \int dV e^{i (\vec{Q} - \vec{P}) \cdot \vec{r}} \\<br /> &amp;= \sum_{\vec{Q},\vec{P}}\frac{N^{2}}{W^{2}} \ (\vec{W}\cdot \vec{Q}) \ (\vec{W}\cdot \vec{P}) \ b_{\vec{Q}}b^{*}_{\vec{P}} \ V \ \delta_{\vec{Q},\vec{P}} \\<br /> &amp;= \sum_{\vec{Q}} \frac{N^{2}V}{W^{2}} \ (\vec{W}\cdot \vec{Q})^{2} \ b^{*}_{\vec{Q}} \ b_{\vec{Q}}<br /> \end{align*}<br />
7) Contributions to energy come from oscillations in the \vec{Q} = \vec{W} directions
<br /> \begin{align*}<br /> H &amp;= \frac{1}{2} n M s^{2} \sum_{\vec{W}} N^{2}VW^{2} \ b^{*}_{\vec{W}} \ b_{\vec{W}} \\<br /> &amp;= \frac{1}{2} n M s^{2} \sum_{\vec{W}} (\frac{2\hbar}{nMVWs}) \ V \ W^{2} \ b^{*}_{\vec{W}} \ b_{\vec{W}} \\<br /> &amp;= \frac{1}{2} \sum_{\vec{W}} \hbar \ W \ s \left( b^{\dagger}_{\vec{W}} b_{\vec{W}} + b_{\vec{W}} \ b^{\dagger}_{\vec{W}} \right) .<br /> \end{align*}<br />
8) Why are you reading this old paper?
 
  • #12
samalkhaiat said:
1)
2) W = |\vec{W}| is the wave number. This is clear from (2.5) H = \sum_{\vec{W}} \hbar W s \ b^{*}_{\vec{W}} \ b_{\vec{W}} .

There is a problem, here: ##|\vec{W}|## is a function of r, while ##\omega## in (2.5) can't be a function of r.
 
  • #13
Let's try this:H_f=\frac{1}{2} \int (M \dot{\mathbf{P}}^2+Ms&#039;^2(\nabla \cdot \mathbf{P})^2)n d\mathbf{r}
=\frac{1}{2}nM \sum_\mathbf{W} ( \mathbf{\dot{P}}_{-\mathbf{W}}(t) \mathbf{\dot{P}}_{\mathbf{W}}(t)+s&#039;^2_\mathbf{W}(-i\mathbf{W}\cdot \mathbf{P}_{-\mathbf{W}})(i\mathbf{W}\cdot \mathbf{P}_\mathbf{W}))
=\frac{1}{2}nM \sum_\mathbf{W}s&#039;^2_\mathbf{W} |(i\mathbf{W}\cdot (\frac{1}{i s&#039;_\mathbf{W}\omega}\mathbf{\dot{P}}_\mathbf{W}+ \mathbf{P}_\mathbf{W}))|^2, as ##\mathbf{\dot{P}}_\mathbf{W} || \mathbf{W}## as it is a longitudinal vector field. We set ##\omega = |\mathbf{W}|##.
So we find that ##B_\mathbf{W}(t)= \frac{1}{i \omega s'_\mathbf{W}}\mathbf{P}_\mathbf{W}+\mathbf{P}_\mathbf{W}##
 
Last edited:

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