A geometry of two dimensions, like the surface of a sphere or an egg, has a single number that characterizes it's intrinsic curvature at each point. The "radius of curvature" is defined as the inverse of the square root of the curvature. In three or higher dimensions, to characterize the curvature in different directions you need more numbers.
One intuitive way to visualize this is in terms of what are called "sectional curvatures". To define a sectional curvature at a point, you choose a 2d tangent plane localized at that point, and shoot out geodesics in all directions emanating from that point and tangent to that plane. This generates a 2d surface in the higher dimensional space or spacetime.
That 2d surface has an intrinsic metric, inherited (i.e. induced) from the metric of the ambient space, and the curvature of that surface at the origin point is the sectional curvature associated with that plane. The collection of sectional curvatures associated with all the 2d planes at a point determines all the information contained in the Riemann curvature tensor at that point.
Now, we can interpret your question as asking what are the sectional curvatures at a point on the surface of the Earth. It we choose, as you suggest, a frame at rest with respect to the surface of the Earth, we could consider for example the sectional curvature associated with a plane tangent to the surface of the Earth, or a vertical plane.
The latter is -2 times the former, and the former is GM/r^3c^2 = g/(c^2r), where r is the radius of the Earth, so the vertical-horizontal sectional curvature is positive, and its curvature radius is√c^2r/g ~ 2 x 10^11 meters, while the horizontal-horizontal sectional curvature is negative, and its curvature radius is 4 x 10^11 meters. [If you add two orthogonal vertical-horizonal curvatures to the horizontal-horizontal one you get zero. This means that the curvature scalar of the spatial geometry in the rest frame of the Earth is zero at the surface, which is correct since the stress tensor vanishes outside the matter of the Earth.]