What part of spherical harmonic coefficients represents physics quantities?

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SUMMARY

The discussion centers on the expansion of spherical functions using spherical harmonics, specifically addressing the interpretation of the coefficients. It is established that the coefficients are complex numbers, and to observe physical quantities, one should focus on the real parts of these coefficients. Additionally, combining spherical harmonics with the same degree l but differing orders m and -m yields real functions, analogous to the combination of exponential functions to form cosine and sine functions. This method is particularly relevant in the context of representing chemical orbitals.

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  • Understanding of spherical harmonics and their mathematical properties.
  • Familiarity with complex numbers and their representation.
  • Knowledge of real functions and their relation to complex functions.
  • Basic concepts in quantum chemistry, particularly regarding atomic orbitals.
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  • Explore the mathematical properties of spherical harmonics in detail.
  • Learn about the application of spherical harmonics in quantum mechanics.
  • Investigate the process of combining spherical harmonics to form real functions.
  • Study the representation of atomic orbitals using spherical harmonics in chemistry.
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Physicists, mathematicians, and chemists interested in the application of spherical harmonics in physical models and quantum chemistry, particularly those working with spherical functions and their coefficients.

susantha
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Hi,
I need expand a spherical function(real function not a complex function) in terms of spherical harmonics. Expansion coefficients are complex numbers. If i need to observe physics quantities that are represented by the spherical harmonics coefficients which part should i look at- real part, complex part or the magnitudes (sqrt(real^2 + imaginary^2) of spherical harmonic coefficients?

Thanks in advance
 
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You can combine the two spherical harmonics with same l but m and -m to get two real functions just like you can combine exp(ix) and exp(-ix) to obtain cos(x) and sin(x). These new functions form a real basis which you can use. You have probably seen them in the representation of the chemists orbitals.
 

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