What rules, energy or entropy?

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    Energy Entropy Rules
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Discussion Overview

The discussion revolves around the relationship between energy and entropy in physical systems, exploring whether systems tend toward maximum entropy or minimum energy. Participants examine these concepts in the context of closed and open systems, thermodynamic laws, and specific examples.

Discussion Character

  • Debate/contested
  • Conceptual clarification
  • Technical explanation

Main Points Raised

  • Some participants assert that any physical system tends toward maximum entropy, while others challenge this by stating that there is no absolute maximum entropy for a system.
  • It is noted that the tendency for a system to reach minimum energy applies only to non-isolated systems, and energy conservation must be accounted for.
  • A participant describes an experiment with iodine gas to illustrate how entropy can overpower energy, suggesting that a uniform distribution of gas is more probable despite gravitational potential energy influences.
  • Another participant questions whether a state of maximum entropy always corresponds to a state of least energy, indicating confusion about the relationship between these concepts.
  • Some participants emphasize the importance of distinguishing between closed and open systems when discussing energy and entropy, noting that energy is conserved in closed systems while entropy cannot decrease.
  • There are discussions about how entropy can be viewed as a measure of disorder, information, or unusable energy, with some participants arguing that these interpretations can lead to different conclusions about the relationship between energy and entropy.
  • Concerns are raised about the clarity of references to closed systems, with participants questioning the implications of energy preservation within such systems.

Areas of Agreement / Disagreement

Participants express differing views on the relationship between energy and entropy, with no consensus reached. Some agree on the principles of thermodynamics, while others contest interpretations and implications of these principles.

Contextual Notes

Participants highlight the need for careful definitions and distinctions between closed and open systems, as well as the implications of energy conservation and entropy increase in various contexts. Unresolved mathematical steps and assumptions about system interactions are noted.

  • #31


One thing you cannot describe a Carnot cycle engine as is a constant volume process. None of the four legs on an indicator diagram occur at constant volume. I do not know of a mechanism (if that is the right word) that is capable of extracting work with the working fluid at constant volume in a carnot engine.

There is a type of heat engine known as constant volume ( or Rochas) cycle engine that has two of the legs vertical (const vol)and two with the adiabatic gamma law expansion.

Another type with a (single) constant volume leg and a single adiabatic leg is the Lenoir gas engine.

However work is only only during the non constant volume parts of each cycle.
 
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  • #32


Studiot said:
One thing you cannot describe a Carnot cycle engine as is a constant volume process. None of the four legs on an indicator diagram occur at constant volume. I do not know of a mechanism (if that is the right word) that is capable of extracting work with the working fluid at constant volume in a carnot engine.

There is a type of heat engine known as constant volume ( or Rochas) cycle engine that has two of the legs vertical (const vol)and two with the adiabatic gamma law expansion.

Another type with a (single) constant volume leg and a single adiabatic leg is the Lenoir gas engine.

However work is only only during the non constant volume parts of each cycle.
We are really going in circles now. Your concerns have nothing to do with whether an isolated system which is not internally in thermodynamic equilibrium will tend toward maximum entropy. I gave you a system that is not in thermodynamic equilibrium and showed you that it will end up in a final state of thermal equilibrium with zero entropy increase.

Why does the heat flow have to occur in a constant volume process? If heat flow occurs in a constant volume process, there will always be a net increase in entropy. It is only if heat flow occurs isothermally that there can be no increase in entropy. That is what occurs in a Carnot engine.

AM
 

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