When is the Ionic Product of Water Constant?

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SUMMARY

The ionic product of water, denoted as Kw, remains constant at a given temperature regardless of the solution's acidity or alkalinity. This means that Kw does not vary in dilute acidic or alkaline solutions, nor does it change at the equivalence point of a strong acid-strong alkali titration. The discussion highlights a misunderstanding regarding the conditions under which Kw is considered constant, emphasizing that the question posed is fundamentally flawed.

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  • Understanding of aqueous chemistry principles
  • Familiarity with the concept of ionic product
  • Knowledge of acid-base titration processes
  • Basic grasp of temperature effects on chemical equilibria
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TT0
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Homework Statement



Under which set of conditions is the ionic product of water, Kw, constant at a given temperature in aqueous systems?

  1. in dilute acidic but not dilute alkaline solutions.
  2. in dilute alkaline but not dilute acidic solutions.
  3. in both dilute acidic and alkaline solutions.
  4. only at the equivalence point of a strong acid-strong alkali titration.
  5. only in pure water.

Homework Equations

The Attempt at a Solution



I don't understand what this question is asking. Is it asking in which scenario is the Kw constant for all temperatures or does it never change? Both of these I don't understand, could someone explain this to me?

Cheers!
 
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Technically there is no correct answer between those given. Kw is constant always.
 
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I see, so its just a bad question then?

Thanks
 
That's my opinion.
 
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