Where Can I Find Reliable Solubility Data for Various Mixtures and Temperatures?

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Discussion Overview

The discussion revolves around finding reliable solubility data for various mixtures, specifically water-toluene, water-hexane, and water-MEK at 40°C, as well as the densities of the pure solvents at the same temperature. Participants are seeking resources and databases that provide this information.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant inquires about a good solubility database, mentioning difficulties in finding specific data from IUPAC-NIST.
  • Another participant suggests that water-toluene and water-hexane may not be miscible, while stating that water-MEK is infinitely miscible.
  • A third participant expresses a desire for actual values rather than approximations.
  • A later reply recommends a book titled "Handbook of aqueous solubility data" as a useful resource on the topic.

Areas of Agreement / Disagreement

Participants do not appear to reach a consensus on the miscibility of the mixtures discussed, and there is no agreement on the availability of the specific data requested.

Contextual Notes

Participants have not specified the exact definitions or conditions under which the solubility data is sought, nor have they clarified the assumptions related to the miscibility of the mixtures.

Serena
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HI,

Do you have any suggestion for a good solubility database? I tried IUPAC-NIST but I can't find the data I need there (water-toluene, water-hexane, water-MEK mixtures at 40°C). I am also looking for the densities of the pure solvents at 40°C.

Thank you
 
Last edited:
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Serena said:
water-toluene
First approximation? "Not?" Ditto water-hexane. Water-MEK is infinitely miscible.
 
Dear Bystander,
Thank you fro your answer. I am looking for actual values.
 
Here a really good book on the topic:

Yalkowsky, Samuel H., Yan He, and Parijat Jain. Handbook of aqueous solubility data. CRC press, 2010.
 

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