Why Do SO2 and XeO4 Form Different Types of Bonds?

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Discussion Overview

The discussion revolves around the bonding characteristics of sulfur dioxide (SO2) and xenon tetroxide (XeO4), specifically focusing on the types of bonds formed and the reasoning behind the bonding structures of these molecules. It includes theoretical considerations and conceptual clarifications regarding octet expansion and the nature of covalent bonds.

Discussion Character

  • Conceptual clarification
  • Debate/contested
  • Technical explanation

Main Points Raised

  • One participant states that sulfur in SO2 forms a double bond with one oxygen and a dative covalent bond with another, while xenon in XeO4 forms double bonds with each oxygen.
  • Another participant asserts that neither sulfur nor xenon extend their octet in these compounds, suggesting that the distinction between double bonded and dative bonded oxygens is fictive.
  • A participant questions the assertion that neither sulfur nor xenon extend their octet, noting that there appear to be 16 outermost electrons around xenon when drawing its electron diagram.
  • One participant mentions the complexity of bonding in these compounds and suggests consulting a specific library resource for further information.
  • Another participant expresses difficulty in understanding the topic and thanks the previous contributor for their input.
  • A participant proposes that since electrons are indistinguishable and move randomly, it may be indistinguishable whether a bond is dative or pure covalent.
  • A later reply suggests a Wikipedia article on hypervalent molecules as a potential resource for clarification.

Areas of Agreement / Disagreement

Participants express differing views on the nature of bonding in SO2 and XeO4, particularly regarding octet expansion and the classification of bonds. The discussion remains unresolved with multiple competing perspectives presented.

Contextual Notes

Participants have not reached consensus on the definitions and implications of dative versus covalent bonds, and there are unresolved questions regarding the electron configurations of sulfur and xenon in these compounds.

asdff529
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The S molecule of SO2 forms a double bond with one O and dative covalent bond with another O
Meanwhile,XeO4 is a molecule which Xe forms a double bond with each O
I have a question here
Why doesn't that S forms 2 double bonds with O to extend its octet structure?
Similarly,why doesn't that Xe form 4 dative covalent bond with O to maintain its octet structure?
 
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Neither sulfur nor xenon extend their octet in these compounds and a distinction between double bonded and dative bonded oxygens is purely fictive.
 
DrDu said:
Neither sulfur nor xenon extend their octet in these compounds and a distinction between double bonded and dative bonded oxygens is purely fictive.

why do u say that "Neither sulfur nor xenon extend their octet in these compounds"
if i draw the electron diagram of Xe,i count there should be 16 outermost electrons around Xe?
 
but can i explain like this:
since electrons are indistinguishable,and they all move randomly around the atoms
so it is indistinguishable whether it is dative or pure covalent?
 

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