Why is silver the best conductor?

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SUMMARY

Silver (Ag) is recognized as the best electrical conductor, followed by copper (Cu) and aluminum (Al), despite the free electron density ranking being the opposite. The conductivity of metals is influenced not only by the density of free electrons but also by scattering mechanisms including phonons, impurities, and defects. Electron-electron scattering, as described by the Landau Fermi Liquid theory, has a minimal impact on conductivity at standard temperatures, becoming significant only near absolute zero.

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iScience
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More specifically, the free electron density in increasing order goes like this:

Ag
Cu
Al

why then is the conductivity in the reverse order? ie the free electron density doesn't seem to play much of a role in conductivity beyond a certain point.
 
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Probably due to electron-electron scattering, if there are too many free electrons then they will collide with each other and limit the conductivity.
 
iScience said:
More specifically, the free electron density in increasing order goes like this:

Ag
Cu
Al

why then is the conductivity in the reverse order? ie the free electron density doesn't seem to play much of a role in conductivity beyond a certain point.

Really? Where did you get the info that the conductivity is in "the reverse order"?

http://chemistry.about.com/od/molec...f-Electrical-Resistivity-And-Conductivity.htm

Secondly, the conductivity isn't just a function of charge carrier density. The resistivity is a function scattering of charge carrier with phonons, impurities, defects, etc. BTW, electron-electron scattering, per Landau Fermi Liquid description, plays a minor role in the conductivity at ordinary temperatures. It is only apparent at extremely low temperature near 0 K.

This probably should have been posted in the Solid State physics forum.

Zz.
 

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