Why is there a negative charge on the oxygen atom with the single bond?

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SUMMARY

The discussion centers on the concept of formal charge in molecular structures, specifically addressing why a negative charge is associated with an oxygen atom in a single bond rather than in a double bond. Participants emphasize the importance of accurately counting electrons, where each dot represents a single electron and each bar indicates a bond with two shared electrons. The correct method involves calculating the total number of electrons for each atom, ensuring that the valence shell of a neutral oxygen atom contains six electrons. Miscalculations in counting were highlighted as a common source of confusion.

PREREQUISITES
  • Understanding of Lewis structures
  • Knowledge of formal charge calculation
  • Familiarity with electron counting methods
  • Basic concepts of covalent bonding
NEXT STEPS
  • Study the principles of Lewis structures and resonance
  • Learn how to calculate formal charge in molecular compounds
  • Explore the significance of electron sharing in covalent bonds
  • Review the valence shell electron count for various elements
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Chemistry students, educators, and anyone seeking to deepen their understanding of molecular structures and electron configurations.

Indranil
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Please post this type of questions in homework section using the template.
ozone_final.PNG

My question is that why is the negative charge on the oxygen atom with the single bond, why not on the oxygen atom with the double bond? I am confused.
Source: https://chem-net.blogspot.in/2012/01/simple-procedure-for-writing-lewis.html
 

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Count the electrons ... (use factor 0.5 for shared electrons)
 
BvU said:
Count the electrons ... (use factor 0.5 for shared electrons)
I don't understand what you mean. Could you make your point easier, please? Could you tell me the method, please?
 
For each atom count electrons "belonging" to that atom, if an electron is shared by two atoms, count it as half.
 
Borek said:
For each atom count electrons "belonging" to that atom, if an electron is shared by two atoms, count it as half.
Still, I don't understand how to count. Could you clarify it, please?
 
Each dot is a single electron, each bar is a bond - so two shared electrons.

How many dots on the left atom? How many shared electrons on the left atom? Just add.
 
Borek said:
Each dot is a single electron, each bar is a bond - so two shared electrons.

How many dots on the left atom? How many shared electrons on the left atom? Just add.
If I count from the left atom with the double bond, 4 dots, and two shared electrons, total electrons are 8. now what to do next, sir?
 
Indranil said:
4 dots, and two shared electrons, total electrons are 8

4+2 is not 8.

How many electrons should be present on the valence shell in a neutral, isolated oxygen atom?
 
It should be 6 electrons. Now what to do next, sir?
 
  • #10
Don't "sir" me.

As I wrote - your calculations are off, correct them. And use the same approach to calculate number of electrons on other oxygen atoms.
 
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  • #11
Borek said:
Don't "sir" me.

As I wrote - your calculations are off, correct them. And use the same approach to calculate number of electrons on other oxygen atoms.
Still, I am confused. Could you calculate, please?
 
  • #12
I am not going to spoon feed you, sorry. You will either try, or you will not learn anything.
 
  • #13
Borek said:
I am not going to spoon feed you, sorry. You will either try, or you will not learn anything.
How to try. could you give me some formula?.
 
  • #14
What formula do you need to count the dots on the picture?
 
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  • #15
Borek said:
What formula do you need to count the dots on the picture?
Formal charge.
 
  • #16
I have no idea what you mean now.

You were told to count electrons, you even did it - you just made a trivial mistake when adding two numbers. Please reread the thread, you were told what to do several times. If you know what the dots and bars on the resonance structure are the task is trivial.
 

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