Why Liquid Boils: Explaining Saturated Vapor Pressure

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SUMMARY

This discussion centers on the concept of boiling and saturated vapor pressure, emphasizing that boiling occurs when the vapor pressure of gas bubbles equals the surrounding atmospheric pressure. The formation of gas bubbles beneath the liquid surface is critical, as these bubbles must maintain pressure equal to or greater than the surrounding fluid to prevent collapse. Participants also explore the effects of liquid density and gravitational pressure on boiling, concluding that boiling can occur when vapor pressure reaches 1.1 times the atmospheric pressure, accounting for factors like bubble surface tension.

PREREQUISITES
  • Understanding of phase changes in liquids and gases
  • Knowledge of vapor pressure concepts
  • Familiarity with atmospheric pressure and its effects on boiling
  • Basic principles of fluid dynamics
NEXT STEPS
  • Research the relationship between vapor pressure and boiling point in different liquids
  • Explore the effects of liquid density on boiling dynamics
  • Study the impact of atmospheric pressure variations on boiling behavior
  • Learn about the role of surface tension in bubble formation during boiling
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Students and professionals in chemistry, physics, and engineering fields, particularly those interested in thermodynamics and fluid mechanics.

netheril96
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It's hard for me to find the why,bcz most books only give this without any explanation

Is there anyone who knows the exact reason?
 
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Boiling refers to the process whereby a phase change from liquid to gas takes place throughout the liquid. This would imply the formation of gas bubbles beneath the liquid surface. That is why bubbling is a characteristic of boiling liquids.

Now, the pressure in the gas bubbles must be at least equal to that of the surrounding fluid and the atmosphere/environment. Otherwise, the bubbles will collapse, and boiling does not occur. Thus, the boiling can only occur at the point where the vapour pressure (of the gas bubbles) equals the pressure of the surroundings.
 


Fightfish said:
Boiling refers to the process whereby a phase change from liquid to gas takes place throughout the liquid. This would imply the formation of gas bubbles beneath the liquid surface. That is why bubbling is a characteristic of boiling liquids.

Now, the pressure in the gas bubbles must be at least equal to that of the surrounding fluid and the atmosphere/environment. Otherwise, the bubbles will collapse, and boiling does not occur. Thus, the boiling can only occur at the point where the vapour pressure (of the gas bubbles) equals the pressure of the surroundings.

I read this sort of thing before.But why don't you calculate the pressure of the liquid due to gravity?Is it neglible?But if the liquid is so dense or the envrionmental pressure is so small that the bubbles some centimeters below the surface is under the pressure significantly larger,say 10%,than that of environmental pressure of the gas above the surface,will it boil when saturated vapor pressure reaches environmental pressure?Or when it reaches 1.1 times the environmental pressure?
 


I think you are right netheril96. It should boil when the pressure reaches 1.1 times the atmospheric pressure(neglecting the pressure difference due to surface tension of bubble).
I think that is why the bubble gets larger as it rises up during boiling. The pressure in the bubble decreases with the height and it gets bigger and bigger, finally reaching to the atmospheric pressure.
 


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