Why Rb85 is difficult to bose-condense?

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Discussion Overview

The discussion centers on the challenges of achieving Bose-Einstein condensation (BEC) with the isotope Rb85 compared to Rb87. Participants explore the underlying reasons for the differences in condensability between these two isotopes, touching on aspects of atomic interactions, scattering lengths, and hyperfine levels.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • Some participants note that Rb87 is easier to Bose-condense due to its positive scattering length, while Rb85 has a negative scattering length, leading to attractive interactions that complicate condensation.
  • It is mentioned that the attractive interaction in Rb85 limits the number of atoms that can condense, as the condensate may contract and collapse with increasing atom numbers.
  • Participants discuss the role of hyperfine levels and how they depend on nuclear moments and nucleon numbers, suggesting this may influence the behavior of the isotopes.
  • One participant raises questions about the behavior of the scattering length and its connection to hyperfine levels, indicating uncertainty about the underlying physics.
  • There is a query regarding the term "contracting" in relation to the condensate, with clarification that it refers to the physical proximity of atoms as attractive interactions increase.
  • Another participant speculates on why a gas with attractive interactions might condense at lower temperatures, suggesting it could accommodate more particles at lower energy without occupying the lowest energy state.
  • It is noted that most bosons used for BEC are composite bosons, and their substructure may become relevant as interparticle spacing decreases.

Areas of Agreement / Disagreement

Participants express varying levels of understanding and uncertainty regarding the mechanisms at play, particularly concerning the scattering length and its implications. There is no consensus on the precise reasons for the differences in condensability between Rb85 and Rb87, indicating ongoing debate and exploration of the topic.

Contextual Notes

Participants acknowledge limitations in their understanding of the scattering length behavior and the implications of attractive interactions on condensation, suggesting a need for further clarification and exploration of these concepts.

wdlang
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some guy told me Rb87 is easy to bose-condense, while Rb85 is very difficult.

i do not why.

i guess these two isotopes share almost the same internal levels and atom-atom interactions.
 
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Recall that the usual trick is to play games with hyperfine levels --- these depend on the nuclear moments and thus the nucleon number.
 
The scattering length for Rb87 is positive while it is negative for Rb85. This means that at low temperature Rb87 atoms will on average repel each other, while Rb85 atoms will on average attract each other. This attractive interaction severely limits the possible number of atoms, which can condense, because the condensate will contract and finally collapse as more atoms are added. However, one can apply a magnetic field near a Feshbach resonance to tune the magnitude and sign of the scattering length to some extent.
 
Cthugha said:
The scattering length for Rb87 is positive while it is negative for Rb85. This means that at low temperature Rb87 atoms will on average repel each other, while Rb85 atoms will on average attract each other. This attractive interaction severely limits the possible number of atoms, which can condense, because the condensate will contract and finally collapse as more atoms are added. However, one can apply a magnetic field near a Feshbach resonance to tune the magnitude and sign of the scattering length to some extent.

Thanks a lot!

I do not even know this fact before.
 
genneth said:
Recall that the usual trick is to play games with hyperfine levels --- these depend on the nuclear moments and thus the nucleon number.

Thanks for directing the way for me.
 
Cthugha said:
The scattering length for Rb87 is positive while it is negative for Rb85. This means that at low temperature Rb87 atoms will on average repel each other, while Rb85 atoms will on average attract each other. This attractive interaction severely limits the possible number of atoms, which can condense, because the condensate will contract and finally collapse as more atoms are added. However, one can apply a magnetic field near a Feshbach resonance to tune the magnitude and sign of the scattering length to some extent.

ok... but:

- why does the scattering length have this behaviour? I guess it is connected to what genneth said but precisely?;

- what do you mean by "contracting"? is it a technical expression?

- why, given an attractive interaction, a gas should condensate at lower temperature then in absence of interaction? (here I think it is because it can host more particles at lower energy without involving the lowest energy state)
 
tirrel said:
- why does the scattering length have this behaviour? I guess it is connected to what genneth said but precisely?;

To be honest, I do not know. I am a "solid-stater". Maybe someone with some experience in atom optics can answer that.

tirrel said:
- what do you mean by "contracting"? is it a technical expression?

The condensate is literally contracting. On increasing the number of atoms, the attractive interaction will increase and they move closer to each other.

tirrel said:
- why, given an attractive interaction, a gas should condensate at lower temperature then in absence of interaction? (here I think it is because it can host more particles at lower energy without involving the lowest energy state)

Might be. Again I am not sure.

Additionally most bosons used to produce BEC are only composite bosons. At large interparticle spacings the substructure will not play a role. However it does as the average distance between particles gets smaller.
 

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