Work Check: Heat transfer between reservoir and small system

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SUMMARY

The discussion focuses on calculating the total change in entropy when a large reservoir at temperature T_r is placed in thermal contact with a small system at temperature T. The user derives the entropy changes for both the system and the reservoir using the heat capacity C. The final expressions obtained are ΔS_sys = C ln(T_r/T) for the system and ΔS_r = (C(T - T_r))/T_r for the reservoir, leading to the total change in entropy being the sum of these two values. The approach utilizes the principles of thermodynamics, specifically the conservation of energy and the concept of reversible pathways.

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  • Understanding of thermodynamics principles, particularly entropy and heat transfer.
  • Familiarity with state functions and reversible processes in thermodynamics.
  • Knowledge of calculus for integrating thermodynamic equations.
  • Basic understanding of heat capacity and its role in energy transfer.
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  • Study the derivation of the first and second laws of thermodynamics.
  • Learn about the concept of reversible and irreversible processes in thermodynamics.
  • Explore the implications of heat capacity in different thermodynamic systems.
  • Investigate the relationship between entropy and the second law of thermodynamics.
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WWCY
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Homework Statement



Could someone look through my work? The parts where I wrote (??) are steps I am especially unsure about.

Many thanks in advance.

A large reservoir at temperature ##T_r## is placed in thermal contact with a small system at temperature ##T##. They end up at temperature ##T_r##. Given that ##C## is the heat capacity of the system, find the total change in entropy in the universe.

Homework Equations

The Attempt at a Solution



I started by looking for the entropy of the system. Since the volumes don't change, I can write
$$ dU_{s} = TdS_{s}$$
Since ##U_{s}## is a state function that depends only on the initial and final states of the system, I take some reversible pathway (??), which means
$$dU_{s} = TdS_{s} = \delta Q_{rev}$$
$$dS_{s} = \frac{1}{T} C dT$$
Integrating gives me $$\Delta S_{sys} = C \ln{\frac{T_r}{T}}$$
Then for the entropy of the reservoir: Conservation of energy, and the fact that the reservoir doesn't change its volume allows me to write (again, using some reversible path [?])
$$dU_{r} = T_{r}dS_{r} = -dU_{s} = -CdT$$
$$dS_{r} = -\frac{1}{T_{r}}CdT$$
Integrating gives me ##\Delta S_{r} = \frac{C(T - T_r)}{T_r}##

The total change is then the sum of these two changes in entropy.
 
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WWCY said:

Homework Statement



Could someone look through my work? The parts where I wrote (??) are steps I am especially unsure about.

Many thanks in advance.

A large reservoir at temperature ##T_r## is placed in thermal contact with a small system at temperature ##T##. They end up at temperature ##T_r##. Given that ##C## is the heat capacity of the system, find the total change in entropy in the universe.

Homework Equations

The Attempt at a Solution



I started by looking for the entropy of the system. Since the volumes don't change, I can write
$$ dU_{s} = TdS_{s}$$
Since ##U_{s}## is a state function that depends only on the initial and final states of the system, I take some reversible pathway (??), which means
$$dU_{s} = TdS_{s} = \delta Q_{rev}$$
$$dS_{s} = \frac{1}{T} C dT$$
Integrating gives me $$\Delta S_{sys} = C \ln{\frac{T_r}{T}}$$
Then for the entropy of the reservoir: Conservation of energy, and the fact that the reservoir doesn't change its volume allows me to write (again, using some reversible path [?])
$$dU_{r} = T_{r}dS_{r} = -dU_{s} = -CdT$$
$$dS_{r} = -\frac{1}{T_{r}}CdT$$
Integrating gives me ##\Delta S_{r} = \frac{C(T - T_r)}{T_r}##

The total change is then the sum of these two changes in entropy.
Looks good. Nice job.
 

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