Why is the work done by an ideal gas the area under a PV diagram?

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SUMMARY

The work done by an ideal gas is represented as the area under a Pressure-Volume (PV) diagram, defined mathematically as dW = P dV. This relationship is physically grounded in the concept that pressure (P) is the force (F) applied per unit area (A), and work (W) is the product of force and displacement (d). The area under the PV curve directly correlates to the energy transferred as work during volume changes, reinforcing that pressure quantifies work done per unit volume change. Understanding this relationship is crucial for analyzing thermodynamic processes under quasistatic conditions.

PREREQUISITES
  • Understanding of thermodynamic concepts, particularly work and energy.
  • Familiarity with Pressure-Volume (PV) diagrams.
  • Basic knowledge of calculus, specifically differentiation and integration.
  • Concept of quasistatic processes in thermodynamics.
NEXT STEPS
  • Explore the derivation of work done in various thermodynamic processes, such as isothermal and adiabatic processes.
  • Learn about the implications of quasistatic conditions on thermodynamic calculations.
  • Investigate the relationship between pressure, volume, and temperature using the Ideal Gas Law.
  • Study the significance of units in thermodynamics, particularly how they relate to energy calculations.
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This discussion is beneficial for physics students, engineers, and anyone interested in thermodynamics, particularly those studying the principles of work and energy in gas systems.

goodcow
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Could someone please prove why the work done by a gas is the area under a PV diagram?

That is, I know that dW=P \text{ }dV, but why is that true physically? I realize that W=f \cdot d \text{ and } F=P \cdot A .Thanks.
 
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You have more or less done it for yourself!
W = P x V...P = F/A and V = A x d
W = F/A x A/d ...= F x d
 
Well yes, I know that the equation is true, but I was wondering why it's physically true. For example, the area under a velocity-time graph is displacement. Why is the area under the graph the work done?
 
It is because the graph is of P against V so the area under this graph must be the PxV quantity...which is Fxd = work done.
 
Oh...wow I'm silly. Thanks!
 
you are in good company!
 
Another way to say all this is that, you understand the area under the v vs. t curve is displacement x because you think of v as dx/dt. Thus, to understand why the area under a P vs. V curve is work done, you simply need to think of pressure as dW/dV, i.e., pressure is the amount of work done per unit volume change. In other words, instead of thinking of work as something that comes from pressure, think of pressure as a concept that stems directly from work. That is very much what pressure is-- the concept of the amount of work done per volume change. Indeed, there are situations where the easiest way to calculate pressure P is to first calculate the work W as a function of V and take dW/dV.
 
just remember that this is true under the assumption of quasistatic conditions, which is almost static but notquite.
think about a situation where the internal pressure is much higher than the external presssure. how do you calculate work then?

thafeera
 
Another little tip: look at the units of the quantities you are multiplying.
P x V units are Pa x m^3 = (N/m^2) x m^3 = Nm = energy units
v x t units are ms^-1 x s = m = distance units
F x e units N x m = energy units
V x Q units are volts x charge = V x C = (J/C) x C = J = energy units
 

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