Assumed value of pressure during quasistatic compression

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SUMMARY

The discussion centers on the quasistatic compression of an ideal gas in a piston, as described in Ian Ford's "Statistical Physics." It establishes that during this process, the force exerted by the gas, represented as pA, equals the external force f applied to the piston. This relationship is valid due to the quasistatic nature of the compression, where the pressure remains uniform and only slightly deviates from the external force, allowing for work to be done as expressed in the equation dW = -p dV.

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  • Understanding of ideal gas laws
  • Familiarity with quasistatic processes in thermodynamics
  • Knowledge of work-energy principles in physics
  • Basic concepts of pressure and force in fluid mechanics
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Students of physics, particularly those focusing on thermodynamics, engineers working with gas systems, and anyone interested in the principles of work and energy in quasistatic processes.

beefbrisket
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My text (Ian Ford - Statistical physics) describes an ideal gas system in a piston being quasistatically compressed by a piston head of area A under external force f. It assumes the system has a uniform pressure p. All good so far. Then it says: "the force pA equals the applied external force f" on its way to showing \text{d}W = -p\text{d}V. I have some feeling that this seems sound but I cannot explain why. Is this just a good approximation we make due to the quasistatic nature of the compression or some other reason? I think they cannot exactly equal otherwise there would be no work done due to zero net force.
 
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beefbrisket said:
My text (Ian Ford - Statistical physics) describes an ideal gas system in a piston being quasistatically compressed by a piston head of area A under external force f. It assumes the system has a uniform pressure p. All good so far. Then it says: "the force pA equals the applied external force f" on its way to showing \text{d}W = -p\text{d}V. I have some feeling that this seems sound but I cannot explain why. Is this just a good approximation we make due to the quasistatic nature of the compression or some other reason? I think they cannot exactly equal otherwise there would be no work done due to zero net force.
If the compression is very slow (quasi static), the force per unit area exerted by the gas on the piston will only be differentially lower than f. So any negative displacement -dx of the piston will result in work -fdx being applied to the gas. But this is just -pdV.
 
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