YAG (Y3Al5O12) opticaly stimulated luminescence

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Discussion Overview

The discussion centers around the luminescence properties of pure YAG (Y3Al5O12) crystals and ceramics, particularly in relation to excitation with a nitrogen laser at 367 nm. Participants seek to understand the luminescence spectra and energy levels associated with this material.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant requests information about the luminescence spectra of pure YAG and energy level diagrams, specifically under excitation at 367 nm.
  • Another participant asserts that pure YAG is transparent at the specified wavelength and questions the reason for luminescence.
  • A participant mentions their research on undoped YAG ceramics, noting that it emits green light when excited by a nitrogen laser, indicating a potential luminescent property.
  • There is a query about whether ordinary crystal YAG exhibits luminescence, suggesting the possibility of impurities affecting the results.
  • A participant points out that ammonium bicarbonate was used as a precipitator, which may introduce small amounts of impurities into the sample.

Areas of Agreement / Disagreement

The discussion contains multiple competing views regarding the luminescence of pure YAG versus undoped YAG ceramics, and whether impurities play a role in the observed luminescence. No consensus is reached on the reasons behind the luminescence properties.

Contextual Notes

Participants have not provided references to support their claims, and the discussion lacks clarity on the specific conditions under which the luminescence is observed. The role of potential impurities remains unresolved.

binomm16
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Hi!

Can anyone help me with information about pure YAG luminescence spectra
(ideal case will be excitation with continuous laser source at 367 nm [Nitrogen] )
or even energy levels diagram?

Thanks in advance
 
Last edited:
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As far as I know pure YAG crystal is transparent at this wavelength. What is the reason for the luminescence do you mean?
 
Well. I haven't found any references on this theme. It's the main reason why I ask this question.
The main topic of my research is YAG ceramics (undoped). And it GLOWS with green light
when I use nitrogen laser as excitation source.
 
And does an ordinary crystal YAG glow? May be there are some admixtures?
 
Ammonium bicarbonate was used as a precipitator. There is possibility of presence of small portion in sample.
 

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