Hess's Law and change of enthelpy

  • Thread starter Thread starter Integral0
  • Start date Start date
  • Tags Tags
    Change Law
AI Thread Summary
The discussion centers on calculating the change of enthalpy for the reaction 2C(s) + O2(g) -> 2CO(g) using Hess's Law. The enthalpy values provided are -393.7 kJ/mol for the combustion of solid carbon to form carbon dioxide and -283.3 kJ/mol for the combustion of carbon monoxide to form carbon dioxide. Initially, there was confusion regarding how to apply Hess's Law to derive the correct reaction equation. After some trial and error, the correct approach was identified: by reversing the combustion reactions and adjusting their enthalpy values accordingly. The final calculation yielded a change in enthalpy of approximately -221 kJ/mol for the reaction, confirming the application of Hess's Law in determining the enthalpy change.
Integral0
Messages
49
Reaction score
0
The enthalpy of combustion of solid carbon to form carbon dioxide is -393.7 kj/mol carbon, and the enthalpy of combustion of carbon monoxide to form carbon dioxide is -283.3 kj/mol CO. Use these data to calculate change of enthalpy for the reaction

2C(s) + O2(g) -> 2CO(g)

----------------------

I'm quite lost . . . after trying this problem for about 20 mins now . . . I still don't see how to use Hess's Law to formulate this answer

What i tried to do was to "form" the equations by the words in the problems.

He are my formulations below; however, I can't seem to get the equation mentioned above.

2CO + O2 -> 2CO2
C + O2 -> CO2

when I rearrange these . . . I can't seem to get 2C(s) + O2(g) -> 2CO(g)

the answer is -220 Kj/mol

thanks
 
Last edited:
Chemistry news on Phys.org


EUREKA! I GOT IT :) :)

2 (C + O2 -> CO2) change in Enthalpy = 2(-394) kj/mol
2CO2 -> O2 + 2CO change in Enthalpy = 2(239.3) kj/mol

= 2C + O2 -> 2CO change in Enthalpy = 221 kj/mol + or - 1 kj/mol

:D ;) :)
 
I want to test a humidity sensor with one or more saturated salt solutions. The table salt that I have on hand contains one of two anticaking agents, calcium silicate or sodium aluminosilicate. Will the presence of either of these additives (or iodine for that matter) significantly affect the equilibrium humidity? I searched and all the how-to-do-it guides did not address this question. One research paper I found reported that at 1.5% w/w calcium silicate increased the deliquescent point by...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!
I'm trying to find a cheap DIY method to etch holes of various shapes through 0.3mm Aluminium sheet using 5-10% Sodium Hydroxide. The idea is to apply a resist to the Aluminium then selectively ablate it off using a diode laser cutter and then dissolve away the Aluminium using Sodium Hydroxide. By cheap I mean resists costing say £20 in small quantities. The Internet has suggested various resists to try including... Enamel paint (only survived seconds in the NaOH!) Acrylic paint (only...
Back
Top