Hybridisation of SO 2 and SeO 2

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The discussion centers on the hybridization of sulfur in sulfur dioxide (SO2) and selenium in selenium dioxide (SeO2). It highlights that sulfur in SO2 is sp2 hybridized due to its discrete gaseous molecular structure, while selenium in SeO2 is sp3 hybridized, attributed to its solid polymeric structure with zig-zag chains. The conversation critiques the explanation in a textbook, questioning the validity of hybridization claims based on bond angles. It emphasizes that SO2 exists only in gaseous form, while SeO2's solid state shows bond angles between 90 and 100 degrees, suggesting that a more straightforward approach without hybridization assumptions might better describe SeO2. The discussion concludes with a recommendation to seek more reliable educational resources.
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Hybridisation of SO2 and SeO2

Why is the hybridisation of S in SO2 sp2 where as it is sp3 in SeO2 ?
 
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Who sais so? Or is this only based on some difference in bond angle?
 


My book.
"SO2 being a discrete molecule exists in the gaseous state. Hybridisation of S in SO2 in the gaseous state is sp2.

Selenium and tellurium dioxides are solids having polymeric chain or layer structure. It consists of a zig-zag chain. Hybridisation of Se in SeO2 is sp3"
 


What does this book want to tell us? That SO2 doesn't exist in liquid or solid form because it is a discrete molecule?
What you can say is that the bond angles in SO2 and SeO2 are about 120 deg in gas phase and in solid SeO2 between 90 and 100 degree. Would be much more honest than speculating about some hypothetical hybridization which is not observable.
In case of SeO2 (solid) assuming no hybridization at all would probably describe the molecule even better.
Get a better book.
 
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