Thermochemistry: Heat of a Solution

In summary, the heat of solution of potassium acetate (KC2H3O2) in water is -15.3 kJ/mol. If 12.7 g of KC2H3O2(s) is dissolved in 525 mL of water at 22.2 °C, the final temperature of the resulting aqueous solution is 21.3 °C. This is calculated using the equation deltaE = C * deltaT, where the initial moles of KC2H3O2 is 0.1294047281 mol and the resulting change in temperature is -0.880897256 °C. It is important to note that a negative heat of solution indicates that heat is absorbed, and therefore the
  • #1
Viralrush
2
0

Homework Statement



The heat of solution of potassium acetate (KC2H3O2) in water is -15.3 kJ/mol.
If 12.7 g of KC2H3O2(s) is dissolved in 525 mL of water that is initially at 22.2 °C, what will be the final temperature (in degrees Celcius) of the resulting aqueous solution?

Homework Equations



Unsure. I used:

deltaE = C * deltaT

The Attempt at a Solution



First calculating moles: 12.7g / 98.1417g/mol = 0.1294047281 mol

Secondly, calculating kJ per mole: 0.1294047281 mol * -15.3kJ/mol = -1.97989234kJ -> -1979.89234 J

Third, sub into equation: -1979.89234J / (4.18 J/g * 537.7g) = deltaT

deltaT = -0.880897256
22.2 degrees - 0.880897256 = 21.31910274

The answer is incorrect. I use an online homework system and the following answers are incorrect:

21.3
21.2
 
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  • #2
If heat of solution is negative, does it mean heat is produced, or absorbed? And should the final temp be higher or lower than initial?

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methods
 
  • #3

1. What is the definition of heat of solution in thermochemistry?

The heat of solution is the amount of heat released or absorbed when a solute is dissolved in a solvent to form a solution at a constant pressure and temperature.

2. What factors affect the heat of solution?

The factors that affect the heat of solution include the nature of the solute and solvent, the concentration of the solute, and the temperature and pressure of the system.

3. How is the heat of solution measured in a laboratory setting?

The heat of solution is typically measured using a calorimeter, which is a device that can accurately measure the heat released or absorbed during a chemical reaction. The solute is dissolved in the solvent in the calorimeter and the change in temperature is recorded.

4. What is the significance of the heat of solution in chemical reactions?

The heat of solution is important in determining the energy changes that occur during a chemical reaction. It can also provide insight into the solubility of a substance and its effect on the surrounding environment.

5. Can the heat of solution be negative?

Yes, the heat of solution can be either positive or negative. A positive heat of solution indicates an endothermic reaction, where heat is absorbed from the surroundings. A negative heat of solution indicates an exothermic reaction, where heat is released into the surroundings.

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