Difference between enthelphy and heat?

In summary, the conversation discusses the relationship between enthalpy, heat, and internal energy in different thermodynamic processes. The difference between enthalpy and heat is clarified, with enthalpy being a property of a substance and heat being a transport phenomenon. It is also noted that in certain situations, such as constant pressure with only expansion work, the enthalpy of the substance is equal to the heat in that specific situation.
  • #1
asdf1
734
0
in my thermodynamics textbook, enthalphy=U+PV
and (delta)heat=(delta)U+(delta)PV
those 2 look the same...
can anybody explain the difference?
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  • #2
Hi asdf1. Take a look at your book again, I think you've taken it out of context. For example, flow through a pipe where heat is added or removed between two points in the pipe is a process in which the heat added/removed is equal to the enthalpy change in the fluid. On the other hand, for the situation where heat is added to a sealed container (ex: a pressurized tank), the amount of heat added or removed is equal to the change in the fluid's internal energy.
 
  • #3
I was taught that enthalpy was a property of a substance. Heat is a transport phenomenon only (i.e. transfer of energy) and that there is no such property as heat.
 
  • #4
at constant pressure with only expansion work the enthalpy of the substance does equal to the heat pertaining to the situation, that is [tex]q_p [/tex]
 
  • #5
thanks! :)
 

1. What is the difference between enthalpy and heat?

Enthalpy and heat are related concepts, but they have different meanings. Heat is a form of energy that is transferred from one object to another due to a temperature difference. Enthalpy is a measure of the total energy of a thermodynamic system, which includes both its internal energy and the work it can do.

2. How are enthalpy and heat related?

Enthalpy and heat are related through the equation Q = ΔH + PΔV, where Q is the heat transferred, ΔH is the change in enthalpy, P is the pressure, and ΔV is the change in volume. This equation shows that the change in enthalpy of a system is equal to the heat transferred to or from the system, plus the work done on or by the system.

3. Can enthalpy be negative or positive?

Yes, enthalpy can be negative or positive. A negative enthalpy change indicates that energy is released from the system, while a positive enthalpy change indicates that energy is absorbed by the system. This is often seen in exothermic and endothermic reactions, respectively.

4. How is enthalpy measured?

Enthalpy is typically measured in joules (J) or kilojoules (kJ). It can be calculated using the equation ΔH = mcΔT, where m is the mass of the system, c is the specific heat capacity, and ΔT is the change in temperature. Enthalpy can also be measured using calorimetry, which involves measuring the heat exchanged during a reaction.

5. What are some real-world applications of enthalpy and heat?

Enthalpy and heat have many real-world applications, including in industries such as chemistry, engineering, and environmental science. For example, enthalpy is used to calculate the energy efficiency of power plants and to determine the amount of energy released during a chemical reaction. Heat is also important in everyday life, such as in cooking and heating our homes.

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