What is Fermi energy: Definition and 104 Discussions

The Fermi energy is a concept in quantum mechanics usually referring to the energy difference between the highest and lowest occupied single-particle states in a quantum system of non-interacting fermions at absolute zero temperature.
In a Fermi gas, the lowest occupied state is taken to have zero kinetic energy, whereas in a metal, the lowest occupied state is typically taken to mean the bottom of the conduction band.
The term "Fermi energy" is often used to refer to a different yet closely related concept, the Fermi level (also called electrochemical potential).
There are a few key differences between the Fermi level and Fermi energy, at least as they are used in this article:

The Fermi energy is only defined at absolute zero, while the Fermi level is defined for any temperature.
The Fermi energy is an energy difference (usually corresponding to a kinetic energy), whereas the Fermi level is a total energy level including kinetic energy and potential energy.
The Fermi energy can only be defined for non-interacting fermions (where the potential energy or band edge is a static, well defined quantity), whereas the Fermi level remains well defined even in complex interacting systems, at thermodynamic equilibrium.Since the Fermi level in a metal at absolute zero is the energy of the highest occupied single particle state,
then the Fermi energy in a metal is the energy difference between the Fermi level and lowest occupied single-particle state, at zero-temperature.

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  1. M

    To calculate Fermi energy from arbitrary dispersion relation

    Homework Statement problem statement is attached as problem.pdf Homework Equations eqn are given in the pdf file The Attempt at a Solution I have tried in vain to connect Fermi energy with dispersion relation. I just don't have any clue ,I also tried to determine the effective...
  2. G

    Fermi energy approximation for white dwarfs

    Hello, I have read several articles/websites which talk about modelling white dwarfs, In all of these papers they state that it can be assumed the electrons have temperature zero, i.e. T<<T_fermi. I haven't been able to find a solid explanation of why this is approximation is possible...
  3. bayan

    Archived CMP. Probability of finding electron with E > fermi energy.

    Homework Statement what is the probability of finding an electron with energy between 5eV and 5.5eV at T=300k, given that the fermi energy of the metal is 4.2 eV. Homework Equations ##P(E,T)dE= \frac{3}{2} E_F^\frac {-3}{2} \frac{E^\frac{1}{2}}{e^\frac{E-E_F}{K_B T}+1}dE## The...
  4. C

    Suppose there is a semiconductor with Fermi energy

    Suppose there is a semiconductor with Fermi energy $E_f$ and that there are $N$ bound electron states. I'd like to know why the mean number of excited electrons takes the form \bar n(T)={N\over \exp\beta(\mu-E_f)+1} where \mu is the chemical potential. ____ I can see that the Fermi...
  5. G

    Fermi energy of nucleus

    How is it that the calculated Fermi energy of neutrons and protons in a heavy nucleus are different, but it's observed that they have the same energy? And how much is the Coulumb repulsion of the protons play a factor in that?
  6. N

    Density of States at the Fermi Energy

    The density of states at the fermi energy is given by D(E_F)=(3/2)n/E_F I understand the density of states is the number of states per energy per unity volume, accounting for n/E_F. I don't understand how the 3/2 multiplying factor accounts for the volume?
  7. E

    A couple questions about energy bands and Fermi energy

    Hello, I'm studying digital integrated circuits and I'm new to solid state physics. I've studied PN junctions, drift and diffusion currents, now I'm trying to see these subjects in terms of energy bands and I'd really appreciate it you could explain to me a couple concepts. When two materials...
  8. S

    Calculating Fermi Energy of Cu

    Hey, My question is displayed below I have had a few questions like these and I just want to check my approach is correct, but I'm not sure - I know that the Fermi Energy of Cu is something like 7eV. Now we are told that there are 4 atoms per cube side - meaning 8 atoms but cubic...
  9. S

    How to Calculate Fermi Energy for a 1D Lattice with 2 Electrons per K-State

    Hey I have a question pictured below: I always seem to struggle with questions like these, my understanding is we know the spacing of K-states throughout the lattice is given by \frac{2\pi}{L} Such that the fermi wavevector divided by this spacing and multiplied by 2 due to the fact...
  10. P

    Fermi Energy and Fermi Level in Semiconductors

    I have searched a lot on the internet for a simple explanation of these two terms. As I have understood these things (quantum physics), after reading from a lot of sources, is that in an atom there are discrete energy levels and electrons occupy the levels according to the least energy of the...
  11. R

    Calculating Fermi Energy for Gold Atoms

    Homework Statement The density of gold (atomic mass 197) is 19.32 g/cm3. Assuming each gold atom contributes one electron to the free electron Fermi gas, calculate the Fermi energy in eV. Homework Equations Fermi energy is given by: E_F=\frac{h^2}{8m_e} \left( \frac{3N}{\pi V} \right)^{2/3}...
  12. B

    The Mystery of Fermi Energy in Accumulation-Mode FETs

    Greetings, I've been doing some literature research and can't seem to find any answers to my question. In an accumulation-mode FET (i.e. only relevant capacitance is that of the gate dielectric), how does one translate the applied gate-voltage to the Fermi energy of the active region? Say we...
  13. fluidistic

    Calculating Fermi Energy in Graphite Using Free Electron Model

    Homework Statement Graphite has a structure of parallel planes weakly interacting with each others such that for many effects it can be considered as two dimensional. Each plane has a hexagonal (honeycomb) structure with a single C atom by site which gives 1 electron of conduction. Assume that...
  14. G

    Calculating Fermi Energy for Magnesium

    Homework Statement Calculate the Fermi energy for magnesium, assuming two free electrons per atom. Homework Equations {E_F} = \frac{{{\hbar ^2}}}{{2m}}{(3{\pi ^2}\rho )^{2/3}}, where \rho = q\frac{N}{V} and q is the number of free electrons. The Attempt at a Solution q = 2, so...
  15. A

    What is the Fermi energy of Liquid He3 at absolute zero?

    Homework Statement The atom He^3 has spin 1/2 and is a fermion. The density of liquid He^3 is 0.081g/cm^3 near absolute zero. Calculate the Fermi energy \epsilon_F and the Fermi temperature T_F Homework Equations \epsilon_F = \frac{\hbar^2}{2m}(\frac{3 \pi^2 N}{V})^{2/3} T_F =...
  16. H

    Density of states, fermi energy

    Homework Statement Consider an electron gas with a density of states given by D(e) = ae2. Here a is a constant. The Fermi energy is eF. a) We first consider the system at zero temperature. Compute the total number of electrons N and the groundstate energy E. Show that the average energy per...
  17. L

    Question: # of particles within an energy range below Fermi Energy.

    Homework Statement Here's what the question says. "Consider a cube of gold 1 mm on an edge. calculate the approximate number of conduction electrons in this cube whose energies lie in the range from 4.000 to 4.025 at 300k. Assume Ef(300K) = Ef(0)." Homework Equations Well, I know...
  18. itaischles

    Fermi energy (in semiconducors) vs. chemical potential

    Hi all, In the solid state physics course I took a year ago we used the chemical potential μ which appeared inside the fermi-dirac distribution function to describe the energy that above it no electrons resides and below it they all reside as the temperature reaches 0 kelvin. Now, when I...
  19. M

    Fermi Energy level with respect to band gap energy

    Homework Statement Calculate Efi with respect to the center of the bandgap in silicon for t= 200, 400, 600 kelvin. Homework Equations ni = Nc e^-((Ec- Ef)/(kt)) k = boltzman constant t= temperature in kelvin Ec = energy level of the conduction band ef= fermi energy level ni=...
  20. T

    Fermi Energy Matching in Semiconductors

    I have taken several courses in semiconductors at the undergraduate level. Both the pure physics part (k vectors) and the more engineering parts (silicon processing, band diagrams) etc. So for all the junctions (Schottky, Ohmic, p-n) - I have never managed to imagine the idea of the Fermi...
  21. R

    Fermi energy (density of electron)

    To find the Fermi energy I need to find the electron density of the material and that I can do by finding the density of atoms in the material in some instances this same density. From what I gather it's not always that way Sometimes you have to multiply a certain number For example...
  22. M

    Quick Fermi Energy QuestionFree electrons?

    Quick Fermi Energy Question..Free electrons?? A quick question on the Fermi energy. From a 3D cubic well, one can derive an expression for the Fermi energy of a solid: Ef = h^2/2m . (3.pi^2.N/V)^2/3 Now, I have come across an expression where N/V, electrons per volume, is replaced by...
  23. B

    Fermi Energy of Non-Interacting Identical Li Atoms in a 3D Harmonic Potential Well

    Homework Statement The degeneracy of the nth level above the ground state for a three dimensional harmonic oscillator is (n+1)(n+2)/2 where n takes values n=0,1,2,... A gas of N non-interacting identical lithium atoms (mass 6amu) each having spin1/2 is confined in a 3d harmonic potential...
  24. M

    Find Fermi Level Pos. of Si w/ 6x1015 Donors & 2x1015 Acceptors @ 300K

    Si is doped with 6 x 1015 cm-3 donors and 2 x 1015 cm-3 acceptors. Find the position of the Fermi level with respect to Ei at 300 K. i know the equations are (for n-type) EF = kT ln(ND/ni) + Ei (for p-type) EF = kT ln(ni/NA) + Ei however, since the problem gives me both donors and...
  25. H

    Finding total energy as a function of the Fermi Energy

    Homework Statement "The numerator of this fraction: \overline{E}=\frac{\int \! E N(E)D(E)dE}{\int \! N(E)D(E)dE} (N(E) is the number of particles in an energy state, D(E) is the density of states) is the total (as opposed to the average particle) energy, which we'll call U_{total} here...
  26. P

    Derive an expression for the Fermi energy of a 2D structure at 0 kelvin?

    Homework Statement That's basically the whole question in the title there, ie; Derive an expression for the fermi energy of a 2d structure at 0 kelvin. 2. The attempt at a solution Basically the first part of the question had us sketching the Fermi-Dirac distribution function at 0K for...
  27. A

    Fermi energy and ratio of the number of occupied levels at an energy

    Homework Statement a) Calculate the Fermi energy for copper. b) Calculate the ratio of the number of occupied levels at an energy of 8.5 eV to the number occupied levels at the Fermi energy at room temperature. c) Based on your answer to a) and b) above, show that at room temperature...
  28. S

    Fermi energy and quasi-Fermi energies in pn-junctions

    Hi, Considering a pn-junction at thermal equilibrium, why does following count EFp=EFn-eVd=EF, where EFp and EFn are the quasi-Fermi energies in the neutral p- and n-type regions before equilibrium is established, with EFn>EFp, EF is the Fermi energy after equilibrium is established...
  29. I

    Fermi Energy & Optical Transitions

    Hello, I have a question which has something to do with band structures etc: A two dimensional solid has two electrons per unit cell. The crystal potential is weak and the solid behaves like a free electron metal. Estimate the threshold for interband optical transitions in terms of the...
  30. B

    What is the relationship between Fermi Energy and Electron Density of States?

    Hello, Im just an amateur physicsist and was interested in Fermi Energy. Found a page http://http://hyperphysics.phy-astr.gsu.edu/hbase/solids/fermi2.html#c1" , that helped. However, I found the page and site a bit hard to understand in some places. Could someone please explain to me...
  31. D

    Fraction of electrons within kT of fermi energy?

    I was reading this website, and I don't understand this last statement. http://hyperphysics.phy-astr.gsu.edu/hbase/solids/fermi.html It reads: "Since only a tiny fraction of the electrons in a metal are within the thermal energy kT of the Fermi energy, they are "frozen out" of the heat...
  32. K

    Intrinsic fermi energy of silicon

    I've tried to look this up online, but I can't find it anywhere. I'm just looking for the intrinsic fermi energy of silicon E_i ? Can someone maybe direct me towards a website where I could look it up? Either that, or is there a way to calculate it from the energy gap for intrinsic silicon...
  33. C

    Effect of Doping on Fermi Energy

    Effect of Doping on Fermi Energy... I was wondering if anyone could give me a clear answer on why doping a semi conductor raises or lowers the fermi energy depending on n or p type semi conductors. There seem to be a few standard ways of explaining this, some to do with charge conservation or...
  34. C

    Effect of Compression on Fermi Energy.

    I know that when a metal is compressed its fermi energy is increased. I would attempt to explain this by saying, "as the volume has been decreased, so has the allowed number of particle in a 3D box states, thus as we have the same number of electrons and fewer allowed states, and the pauli...
  35. S

    How Does the Fermi Energy of Bare Protons Influence Chemical Reactions?

    As I know chemical potential of two reacting substances strongly depends on difference in Fermi energy between them. Fermi energy is inversely proportional to the mass of particles. Does that mean that Fermi energy of bare proton will be 2000 time smaller than that of electron? Usually...
  36. B

    Fermi Energy, number of electrons and holes

    Fermi Energy, Quantum mechanics Electron levels and degeneracies thereof in a system are: W1 = 0 eV, 10^23 /cm3 Valence band W2 = 0.9 eV, 5x10^20 /cm3 Donor level W3 = 1 eV, 2x10^23 /cm3 Conduction level Total number, n, of electrons in the system is (10^23 + 5 x 10^23)...
  37. C

    Chemical Potential & Fermi Energy

    Hi there, i've already read some topics in this forum about the fermi-energy/chemical potential. I've also read the article "The chemical potential of an ideal intrinsic semiconductor" from Mark R. A. Shegelski which made the whole thing a little bit more clear to me. but there are some...
  38. J

    What is the Fermi energy of metallic potassium at 0K?

    Homework Statement We must calculate the Fermi energy of metallic potassium at 0K. We have aleady found the number of atoms per m cubed, we are told that each atom contributes one electron to the free electron gas. Homework Equations Fermi energy = ((hbar^2)/2m)(((3Pi^2)N)/V)^3/2 The...
  39. V

    Fermi Energy of 40P 50N Nucleus Sphere

    Homework Statement I am wondering about something: Calculate the Fermi energy for the neutrons confined to a nucleus with 40 protons and 50 neutrons which roughly forms a sphere of radius 4.6 10^(-15) m. Homework Equations the formula of the fermi Energy is EF=...
  40. V

    Calculating Fermi Energy for Neutrons Confined to a Nucleus

    I am wondering about something: Calculate the Fermi energy for the neutrons confined to a nucleus with 40 protons and 50 neutrons which roughly forms a sphere of radius 4.6 10^(-15) m. the formula of the fermi Energy is EF= ((h-bar)^2*(3*pi^2*n)^(2/3))/2m m:mass of electron, n = number...
  41. H

    Fermi Energy in 2D: Find Relation w/ 3D E=h(cut square)k(square)/2m

    relation of fermi energy in 3D is E=h(cut square)k(square)/2m, if i want a relation of fermi energy in 2D,what should i do?
  42. C

    Exploring Fermi Velocity and Its Relation to Fermi Energy

    Hi, Is this right: Fermi velocity is the velocity of electron-wave in a conductor. Why is it called Fermi velocity, i.e. what is its relation with Fermi energy, etc.. Thanks a lot. Cheers
  43. C

    Understanding Fermi Sphere: Deriving Fermi Energy

    Hi all, I'm studying on the current transfer at quantum level and I have a point that is not so much clear. While reading the Fermi sphere from the book "Current at the nanoscale", I could not understand the expression: The number of electrons in the conductor, N, is the ratio of the...
  44. C

    Fermi energy - Quantum mechanics.

    Homework Statement (I copy-pasted the question) Consider N non interacting electrons inside a 3D box similar to the one we saw in class, but this time it is not cubical, i.e. Lx = Ly \neq Lz. 1. Calculate the fermi energy as a function of N;Lx;Lz;me... 2. What happens if we take Lz --> 0...
  45. S

    About Fermi energy and Fermi temperature

    In classical statistical mechanics, temperature of a system is the measure of its average kinetic energy. In quantum statistical mechanics, Fermi energy corresponds to last filled level at absolute zero and corresponding temperature is the Fermi temperature. Is the Fermi temperature also take...
  46. P

    Fermi energy level in terms of Na and Nd the concentration of dopant?

    fermi level?? is there any relation ( equation) that give the fermi energy level in terms of Na and Nd the concentration of dopant??
  47. T

    Distribution of electrons below the Fermi energy

    I feel dumb that I can't figure this out. I'm sure its something simple that I'm just not seeing, but its really frustrating. Homework Statement How many electrons (in percent of the total number of electrons per mole) lie KbT (ev) below the Fermi energy? Take Ef=5eV and T=300K...
  48. S

    Solving the Fermi Energy of Copper: Momentum, Wavelength, Velocity

    please help me solve this... fermi energy of copper is 7eV. what is the fermi momentum of an electron in copper? what is the de Broglie wavelength of the electron? what is the fermi velocity?/// please help/////:cry:
  49. N

    Doping of semiconductors and fermi energy.

    I understand the principle behind p and n type doping, but I don't understand how such a small amount, 1ppm, can cause such a massive change in the fermi energy. as I understand it: for the intrinsic case the number of electrons exactly matches the number of holes and the fermi energy...
  50. V

    Please share with me about your thinking on Fermi Energy

    In metal, fermi energy is the highest energy states that electron occupied at T=0. And so, fermi energy of a particular metal is an intrinsic value, and won't be changed. Then for a semiconductor, What is fermi energy, is there any concrete interpretation as of metal? Why is it just in the...
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