What is Molecule: Definition and 461 Discussions

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.

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  1. edpell

    Hydrogen molecule in a small box, thought experiment

    What would happen if we placed a hydrogen molecule in a box with sides less than the Bohr diameter. That is, a box so small the electrons could not orbit around the protons at a distance of a Bohr radius. What state would the two electrons and two protons take?
  2. C

    Can We See Atoms and Molecules? Exploring the Latest Real Images

    Can someone post the most precise atom or molecule real pictures at present?
  3. S

    Estimating the vibrational frequency of Hydrogen molecule

    Homework Statement A diatomic molecule, when excited, can vibrate in such a way that the relative distance between the two atoms, r(t), executes periodic oscillations. If the potential energy of the molecule as a function of r is given by V (r), the time dependence of r(t) is identical to...
  4. D

    Molecule collisions in an Ideal Gas

    Homework Statement Molecules in an ideal gas collide with each other at random times. The probability distribution governing the time between collisions is P(t) = Ae^(-bt). (a) Find the value of A so that P(t) is correctly normalized. (b) Find the average time between collisions, t. This...
  5. M

    Coulomb Energy in the KI Molecule: Solving for Separation Distance

    The ionization of potassium is 4.34 eV; the electron affinity of iodine is 3.06 eV. At what separation distance will the KI molecule gain enough Coulomb energy to overcome the energy needed to form the K^+ and I^- ions? I'm looking at the solution to this problem and I'm not understanding how...
  6. L

    What Molecule is Attributed to Patience?

    Do you have any idea what molecule this is? They say it is attributed to patience. Thank you! :)
  7. D

    Energy of a Hydrogen Flouride molecule in normal mode vibration

    Homework Statement Hi everyone! first post here :) Basically, the question is as follows: Consider a hydrogen fluoride molecule (atomic mass of H is 1g/mole and of F is 19 g/mole). 1. Write the energy of the system in terms of the displacements of both atoms. There are other questions...
  8. nukeman

    Can someone me understand pH levels (Meaning mainly for certain molecule)

    Hey, I am trying to figure out some research for a department at school, and need some chemistry info. Basically, I am comparing D2O (Heavy water) HDO (Semiheavy water) and H2O (Light water) NOW... each of them have different pH levels. What does that mean that they each have...
  9. nukeman

    Question about vibrational quality of a molecule (like Deuterium Oxide) ?

    I can't seem to find an answer to this. The question is: If I obtained Deuterium oxide from let's say a plant that manufactured it in some part of the world, and then obtained Deuterium from another plant manufactured from some other place in the world, is it possible for them to have...
  10. M

    The Electron Velocity Needed To Ionize Oxygen Molecule

    Hi , If I used electrons to ionize Oxygen gas by accelerating the electrons and then collide with Oxygen molecules , What is the electron velocity needed to do this ionization ?
  11. B

    What is the electric force of the molecule on the proton?

    Homework Statement An ammonia molecule (NH3) has a permanent electric dipole moment 5.0 x 10^-30cm. A proton is 2.50nm from the molecule in the plane that bisects the dipole. What is the electric force of the molecule on the proton? Homework Equations F = QE = eE_yj =...
  12. W

    QM: two protons of H2 molecule

    Hey, I cannot solve this problem. Please help me. In the H2 molecule, the Pauli exclusion principle demands that the wavefunction of two protons be antisymmetric under the interchange of the two proton coordiates. Based on this, explain the (a) In the spin-triplet states of two protons...
  13. M

    Simplest self-replicating molecule?

    Can you help me identify simplest naturally occurring self-replicating molecule? Or even better, let's make one artificially... where "self-replicating molecule" is such that contains at least two different atoms, it reacts with other atoms and molecules so that it accumulates duplicates of...
  14. N

    Sketching this function for potential energy of two atoms in a molecule

    Homework Statement The potential energy of two atoms in a molecule can sometimes be approximated by the Morse function, where r is the distance between the two atoms and A, R, And positive constants with S<<R. Sketch this function for 0<r<∞... ##U(r) = A ( (e^{(R-r)/(S)}-1)^2 - 1) ## This is...
  15. O

    Force of kinesin molecule within cells

    Homework Statement Within cells, small organelles containing newly synthesized proteins are transported along microtubules by tiny molecular motors called kinesins. What force does a kinesin molecule need to deliver in order to accelerate an organelle having mass 0.028 pg from rest to 2.8...
  16. M

    Oscillation of one molecule or atom

    Hello all, Many Physics texts simply say that atoms "vibrate" when heat energy is transfer to a metal bar when it is heated. Or that molecules vibrate as the result of heat transfer. I'm trying to understand what makes an atom or molecule "move" or oscillate when energy is given to it. If I...
  17. O

    Name the following molecule (common name and IUPAC)?

    http://img43.imageshack.us/img43/2916/95953925.jpg I understand molecule #1 is sec-pentylcyclohexane But how would you call molecule 2? Please give common and IUPAC names (no need for too much detailed explanations) Thank you.
  18. L

    Verifying Eigen Solutions for H2 Molecule

    Eigen - problem for atom ##1## (\frac{p^2_1}{2m}-\frac{e^2}{2\pi\epsilon_0r_{1a}})|\varphi_a^{(1)} \rangle=E_a|\varphi_a^{(1)}\rangle for atom ##2## (\frac{p^2_2}{2m}-\frac{e^2}{2\pi\epsilon_0r_{2b}})|\varphi_b^{(2)} \rangle=E_b|\varphi_b^{(2)}\rangle When I write |q...
  19. B

    Chemistry Ionizing a covalently-bonded molecule?

    Homework Statement What happens to a water molecule if it is hit by a high energy electron or photon?Homework Equations The Attempt at a Solution My knowledge of chemistry is very limited, and my guess is that it would be ionized: e + H_2 O \rightarrow H^+ + OH + 2e Here, a high energy...
  20. S

    Strength of a bond in a molecule

    √Homework Statement Carbon monoxide molecule, which has a reduced mass of 6.85 amu, absorbs infrared radiation wavelength of 4.6um. if the absorption is due to vibrational transitions, calculate the strength of the bond in molecule Homework Equations u=(m1*m2)/(m1+m2) The Attempt at...
  21. A

    How to calculate the energy of the bonding state of a hydrogen molecule?

    How to calculate the energy of the bonding state and antibonding state of a hydrogen molecule? and also how to plot the bonding and antibonding wavefunctions. I have solved Ψ(r,θ,Φ) for a hydrogen atom. and calculated the energy states of it with complete analytical approach. now, i need to...
  22. A

    Energy state of hydrogen molecule

    I am doing my research on quantum transport. Now, I have some confusions- my questions and my idea about those go like this- 1. what is the ground energy state of hydrogen molecule? >> as long as i know, hydrogen molecule has a bonding state and an antibonding state. i think bonding state has...
  23. M

    Predicting the pKa of a molecule

    Heres the question: http://img266.imageshack.us/img266/5071/sar2.png I have no idea how to answer either of these questions. I know that the methyl group attached to the carboxyl groups alpha carbon will decrease the acidity due to electron donating properties. It doesn't look like the...
  24. A

    Velocity Distribution function of molecule at low temperature

    Dear all, In classical molecular dynamics simulation initial velocities are generated using the so called Maxwell distribution. At low temperature it's no longer effective, so I'm wandering whether there is a similar way to generate velocities at low temperature taking into account quantum...
  25. M

    Water molecule absorbing radiation (or not?)

    Hi My current understanding is of a water molecule able to absorb radiation by a transition, a change in the vibration or rotation. But if we consider that the molecule has three axes of rotation, surely one of these axis can be parallel to the molecular dipole, so shouldn't it be impossible...
  26. A

    X(t) of a diatomic molecule with given v_0

    Homework Statement Two identical carts (of mass m) are free to move on a frictionless, straight horizontal track. The masses are connected by a spring of constant k and un-stretched length l_{0}. Initially the masses are a distance l_{0} apart with the mass on the left having a speed v_{0} to...
  27. AakashPandita

    Polarity in water molecule and electronegativity of oxygen in that molecule.

    H20 is polar in nature. It is fundamentally because oxygen is more electronegative than hydrogen and the shared electrons tend to be near oxygen. This may be because the atomic number of oxygen is more than that of hydrogen. But in the bond I don't understand how the 2 shared electrons...
  28. G

    Can the geometry of an iron nucleus explain its unique properties?

    I have heard that iron is quite special in that no matter how much temp. and pressure is present, it will not change to a molecule of greater atomic number. I keep wondering about the geometry of the arrangement of protons and neutrons in the iron atoms' nucleus that could account for this...
  29. J

    Year 12: Cambridge Physics Problems (Joule's classification on molecule factor)

    Derive an expression for the number of impact of gas molecules on unit area in unit time in terms of the number of molecules per unit volume, n, and their mean speed, <c>. Explain the assumptions you make. A disc of radius "a" rotates with constant angular velocity "omega" in a gas at low...
  30. J

    Energy to separate one molecule of water from a single neighbour

    Question: The amount of heat required to convert 1g of ice into vapour is approx. 3000J. Estimate the energy required to separate one molecule from a single neighbour, assuming that in ice, each H2O molecule has four nearest neighbours. [Mr(water) = 18) My reasoning: 3000 x 2 / [1/18...
  31. A

    Why is there a sin^2(theta) factor in the diatomic molecule Hamiltonian?

    Homework Statement I have to find the hamiltonian for a diatomic molecule, where the molecule can only rotate and translate and we supose that potencial energy doesn't change.Homework Equations The Attempt at a Solution Okey so I used Spherical coordinate system such as the kinetic energy of...
  32. fluidistic

    HCl molecule, rotational and vibrational energy question

    Since the HCl molecule has a non vanishing dipole moment, it is allowed to have pure rotational spectrum. If I understand this correctly then it's possible to excite the molecule in such a way that its vibrational energy stays the same while its rotational energy increases by some amount. This...
  33. fluidistic

    Equipartition theorem and molecule of CO

    If I understand the equipartition theorem more or less well, if I heat up a gas then the energy I have spent to heat it up should be equally distributed to the rotational part and vibrational part of the molecule dynamics. Let's take the molecule of CO, I think it has 5 degrees of freedom. 3...
  34. D

    Rotation energy in a ball symmertical molecule, why only two axis?

    I was just wondering that when we have a molecule, and you introduce heat, the molecule starts to get translation, rotation and vibration energy. I'm considering just a molecule with two atoms and one axis which binds them together. Now the real question is that why is there only two axis in...
  35. P

    Chemistry Beers Law, maximum molar absorptivity of carbonyl molecule

    "Given that the maximum molar absorption coefficient of a molecule containing a carbonyl group is 30 dm3 mol-1 cm-1 near 280 nm, calculate the thickness of a sample that will result in (a) half the initial intensity of radiation, (b) one-tenth the initial intensity." My attempt: What is...
  36. W

    Electronic partition function for molecule with degeneracies

    Homework Statement A atom had a threefold degenerate ground level, a non degenerate electronically excited level at 3500 cm^-1(setting the energy orgin as the ground electronic state energy of the atom ) and a threefold degenerate level at 4700 cm^-1 . Calculate the electronic partition...
  37. H

    Feynman ammonia molecule states

    I'm trying to follow Feynman's explanation on page 9-3 of Volume 3 of The Feynman Lectures on Physics. I've attached a copy of the section in question. To normalize CII he notes that < II | II > = < II | 1 >< 1 | II > + < II | 2 >< 2 | II > = 1 I am not clear how he derives the conclusion...
  38. D

    Claisen Rearrangement for this molecule

    Hey all, I'm new here, but used to frequent in high school when I was having a lot of trouble with Physics. Now I'm taking O Chem and figured this could be a great resource to use again. I had this question on a quiz today, just wondering if I did the Claisen rearrangement for this particular...
  39. F

    Specific Heat of Nitrogen Molecule

    Homework Statement Estimate the precise value for the specific heat of a nitrogen molecule at T=13.6K Homework Equations I'm pretty sure the correct equation is: Cp = (7/2)*R + R((hv)/(kT))2 *((e(hv/kT))/(e(hv/kT)-1)2 So R=8.314 J K-1mol-1 T=13.6K h=6.626*10-34m2kg s-1...
  40. B

    Rate of displacement of individual gas molecule help

    Has anyone made a calculation for example, how much (or the mean) time it takes for an individual gas molecule to be displaced a distance of one meter (measured straight) from its original location? For example, air molecule at ambient pressure with a mean free path of 68 nm. That would be...
  41. DaveC426913

    Identifying a Molecule - C8H8N4O2

    Just saw a molecule on TV. It was a tattoo. Want to identify it. C8H8N4O2 Is there a way of researching it? Or I guess I can just give up and ask...
  42. R

    Does a molecule really take on the shape like the VSPER model?

    Is the VSEPR model a tool to help us visualize what is happening to molecules, or do the atoms really take on the shape of something like a trigonal bipyramidal?
  43. M

    Dissociation energy for the NO molecule

    Hi, Does anyone know where I can find post-hartree-fock calculation benchmarks for dissociation energy of the NO molecule. Or even just the equilibrium energy of the NO molecule? I am looking for cc-pVTZ basis set results but I can only seem to find augmented basis set results. Thanks.
  44. A

    E-field of a molecule on a point

    Homework Statement http://postimage.org/image/cky823nof/ Homework EquationsE=kq/r^2 The Attempt at a Solution I figured I would just find the electric field produced at point * by each individual charge and then add them. For example if I were to set E1 to be the top molecule the field...
  45. S

    Discover the Cutting-Edge Technology of the Single Molecule Car at BBC News"

    http://www.bbc.co.uk/news/science-environment-15637867" Cool or what.
  46. V

    Finding the Normal Modes of a 3 mass molecule connected by springs

    Homework Statement Hi everyone! I'm trying to solve a problem involving 3 equal masses (m) arranged in a 45-45-90 right triangle, each mass connected to the other two by a spring, and all the springs have the same spring constant (k). So it should look like this: Where I have made a...
  47. C

    How to graph potential energy for 2 atoms in diatomic molecule w/ 3 unknowns

    Homework Statement The potential energy of two atoms in a diatomic molecule is approximated by U(r)=a/r^12 - b/r^6, where r is the spacing between the atoms and a and b are positive constants. Find the force F(r) on one atom as a function of r. Make two graphs one of U(r)...
  48. 1

    Center of mass of NH3 molecule, not quite there

    Homework Statement An amonia NH3 molecule in the figure has three hydrogen atoms, which form a equilateral triangle as the base of a pyramid. At the top of the pyramid is the nitrogen atom. The length between any two hydrogen atoms is 9.4x10^-11, the length from nitrogen to any of the...
  49. J

    Desnity matrix method to calculate polarizability of H2 molecule.

    Homework Statement Have a H2 molecule in a constant E field. This produces a shift in the on site energies of the 2 H atoms so they have energies ε-δ,ε+δ. δ is proportional to field strength. 1)Calculate the tight binding density matrix when the hopping integral is -1. (γ=-1) δ is positive...
  50. A

    How do you calculate the temp at which a H2O molecule splits into single atoms?

    Hi I want to figure out how to calculate the temperature at which more energy is required to keep hydrogen and oxygen together (as in the case of H2O) than to separate them...in other words the temperature at which hydrogen and oxygen will no longer combine due to extreme temperatures. How...
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