What is Oxidation: Definition and 208 Discussions

Redox (reduction–oxidation, pronunciation: RED-oks or REE-doks) is a type of chemical reaction in which the oxidation states of atoms are changed. Redox reactions are characterized by the actual or formal transfer of electrons between chemical species, most often with one species (the reducing agent) undergoing oxidation (losing electrons) while another species (the oxidizing agent) undergoes reduction (gains electrons). The chemical species from which the electron is removed is said to have been oxidized, while the chemical species to which the electron is added is said to have been reduced. In other words:

Oxidation is the loss of electrons or an increase in the oxidation state of an atom, an ion, or of certain atoms in a molecule.
Reduction is the gain of electrons or a decrease in the oxidation state of an atom, an ion, or of certain atoms in a molecule (a reduction in oxidation state).Many reactions in organic chemistry are redox reactions due to changes in oxidation states but without distinct electron transfer. For example, during the combustion of wood with molecular oxygen, the oxidation state of carbon atoms in the wood increases and that of oxygen atoms decreases as carbon dioxide and water are formed. The oxygen atoms undergo reduction, formally gaining electrons, while the carbon atoms undergo oxidation, losing electrons. Thus oxygen is the oxidizing agent and carbon is the reducing agent in this reaction.Although oxidation reactions are commonly associated with the formation of oxides from oxygen molecules, oxygen is not necessarily included in such reactions, as other chemical species can serve the same function.Redox reactions can occur relatively slowly, as in the formation of rust, or much more rapidly, as in the case of burning fuel. There are simple redox processes, such as the oxidation of carbon to yield carbon dioxide (CO2) or the reduction of carbon by hydrogen to yield methane (CH4), and more complex processes such as the oxidation of glucose (C6H12O6) in the human body. Analysis of bond energies and ionization energies in water allow calculation of the redox potentials.

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  1. J

    Oxidation number vs. ionic charges

    what is the difference between oxidation number and ionic charges? I realize they are written differently, +1 vs. 1+, but how can I reasonably explain the differnces to 17 year olds (and myself?)?
  2. G

    Exploring the Reaction of Potassium and Oxygen: Superoxide Formation

    Oxidation: Is there any reason for Potassium to react with excess oxygen to give a superoxide, not simple or pero-? Gary
  3. J

    Oxidation + Reduction Half-Reactions

    Hello, I was curious if anyone could explain to me the simple procedure/guidleines to carrying out oxidation (half-reactions), reduction (half-reactions) and overall net reactions. I've read my Chem book over and over, but I don't quite understand it. Even a pointer to a good site with a...
  4. ShakeWell

    Selenium Oxidation State in Redox Reaction

    Redox question: 12.53 ml of .05093 M selenium oxide (SeO2) reacted exactly with 25.52 ml of .1 M CrSO4. Cr+3 is formed. To what oxidation state is Selenium converted? I think that the ml + M stuff gives you the ratio between moles of SeO2 and moles of CrSO4 (1m SeO2 = 4m CrSO4). But how am...
  5. M

    Oxidizing Primary Alcohol to Aldehyde in Methylenechloride & DMF

    My problem is to describe the reason why a primary alcohol with PDC in Methylenechloride is oxidized to the aldehyde, but in DMF further to the Acid. Would the only reason be that DMF is hygroscopic and contents usally some water to give the aldehydehydrate?
  6. M

    Reoxidation of TPAP by NMO After Oxidation of Alcohol

    Hi, Denis is my name. Study chemistry in Germany. Have to know the mechanism of the reoxidation to TPAP by NMO after TPAP has oxidized an alcohol. Could you help me? Thx, Denis
  7. Y

    What Determines the Oxidation States of Aluminum and Silicon?

    Oxidation States Help. URGENT! Hey, I've got this question to answer, any help would be greatly appreciated. In a compound, aluminum (Z=13) exists in only the +3 oxidation state but silicon (Z=14) can exist in either the +2 or the +4 oxidation state. Why?
  8. K

    Preparation of butanone by oxidation

    I've done an experiment on preparing butanone by oxidation of butan-2-ol. Here are the simplified procedures. 1. Sodium dichromate-2-water were acidified by few cm^3 concentrated sulphuric acid, then the acidified dichromate and butan-2-ol were mixed. 2. Few pieces of anti-bumping granules...
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