What is Oxidation: Definition and 208 Discussions

Redox (reduction–oxidation, pronunciation: RED-oks or REE-doks) is a type of chemical reaction in which the oxidation states of atoms are changed. Redox reactions are characterized by the actual or formal transfer of electrons between chemical species, most often with one species (the reducing agent) undergoing oxidation (losing electrons) while another species (the oxidizing agent) undergoes reduction (gains electrons). The chemical species from which the electron is removed is said to have been oxidized, while the chemical species to which the electron is added is said to have been reduced. In other words:

Oxidation is the loss of electrons or an increase in the oxidation state of an atom, an ion, or of certain atoms in a molecule.
Reduction is the gain of electrons or a decrease in the oxidation state of an atom, an ion, or of certain atoms in a molecule (a reduction in oxidation state).Many reactions in organic chemistry are redox reactions due to changes in oxidation states but without distinct electron transfer. For example, during the combustion of wood with molecular oxygen, the oxidation state of carbon atoms in the wood increases and that of oxygen atoms decreases as carbon dioxide and water are formed. The oxygen atoms undergo reduction, formally gaining electrons, while the carbon atoms undergo oxidation, losing electrons. Thus oxygen is the oxidizing agent and carbon is the reducing agent in this reaction.Although oxidation reactions are commonly associated with the formation of oxides from oxygen molecules, oxygen is not necessarily included in such reactions, as other chemical species can serve the same function.Redox reactions can occur relatively slowly, as in the formation of rust, or much more rapidly, as in the case of burning fuel. There are simple redox processes, such as the oxidation of carbon to yield carbon dioxide (CO2) or the reduction of carbon by hydrogen to yield methane (CH4), and more complex processes such as the oxidation of glucose (C6H12O6) in the human body. Analysis of bond energies and ionization energies in water allow calculation of the redox potentials.

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  1. S

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    I would like to oxidize suspended elemental sulfur to sulfate in a solution. Any suggestions?
  2. L

    How to predict which elements will have a certain oxidation state?

    Homework Statement I have a test coming up and some of the practice questions were things like "Name 6 elements with a maximum oxidation state of +7" or some other number like +8, +6, etc. How do I go about doing this? The Attempt at a Solution There is the obvious trick of counting...
  3. G

    Organic Chem - Oxidation and Reductions

    Homework Statement Im having some problems with some oxidation and reduction mechanisms. I am not sure if I am doing them correctly. Homework Equations 1. O=C=O + CH3-MG++I- 2. Acetone + NH4+, Na+ H3BCN The Attempt at a Solution 1. I break one of the bonds from the oxygen...
  4. U

    How oxidation effects band structure of metals?

    Hi everyone, I'm working on random materials which are coincidencely oxides and showing semiconductor behaviour... Some of these are metals and i suddenly realize MOS (which are practically everywhere). I know them, i know how they work and behave still i can't get to understand the effect of...
  5. J

    Exploring Zirconium Use in Reactors: Hydrogen & Oxidation

    Few things I'm curious about regarding zirconium use in reactors. I know at high temperatures it can release hydrogen from water by forming zirconium oxide. But: http://en.wikipedia.org/wiki/Zircaloy" this suggests that once a surface layer is formed no more oxidation can take place...
  6. J

    Radiolytic Oxidation: Mechanism & Effects on Nuclear Graphite

    Could someone explain the mechanism of radiolytic oxidation to me? There seems to be very little information available on the net. It is mentioned on http://www-pub.iaea.org/MTCD/publications/PDF/te_1521_web.pdf" :
  7. A

    Oxidation of Alcohols (KMnO4) - Preferred Reactions?

    Given that KMnO4 oxidises primary alcohols to aldehydes and secondary alcohols to ketones, and that in a mixture secondary alcohols will oxidise first (correct?). What's the order of preference of primary alcohols that will most readily oxidise first. The highest molecular weight first...
  8. J

    Computational chemistry of oxidation inhibitors

    I am currently working on a project analysing inhibitors of a heme enzyme which oxidises an indole molecule. We have data on halogenated and non halogenated indoles (methyl, hydroxy, amino and nitro). I have split them into these two classes because the first group have a negative correlation...
  9. W

    What is the Oxidation State of Ti in TiO2?

    Hi there! I have a quick question that could use some clarification. According to my textbook, an oxygen atom has an oxidation state of -1 when in the polyatomic ion peroxide, although it's -2 in most other cases. However, I've come across this problem where it asks for the oxidation state of Ti...
  10. P

    Medical Questions about fats, cholesterol, oxidation, and heart disease

    Just have a few questions about the cause of heart disease and oxidation of fats. I am looking for some studies that relate to the questions if possible. 1. Does saturated fat cause atherosclerosis or is it the oxidized cholesterol that usually accompanies it (as in most cooked animal...
  11. M

    Transition metal oxidation states

    Hi Why does Ni only form NiO with oxidation state of +2 whereas the other transition metals form a wide range of oxides with variable oxidation states Thanks
  12. P

    Sacrificial Anodes and Oxidation Number of KMnO4

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  13. M

    Oxidation states of manganese and pH

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  14. W

    Prevention of Steel Oxidation: Cathodic or surface coating?

    Hello- I recently etched an Altoids tin. I would like to leave the etched tin in an outdoor location as a memorial to something. The etching includes text, and I am worried about oxidation of the steel ruining the tin quickly. I would ideally like for this to last several years (as long as...
  15. J

    Oxidation in Processor Making: Purpose & Repeating?

    What is the purpose of oxidation during the process of making processor? Is it repeatedly perform, like photography?
  16. r-soy

    Q in Oxidation and reduction I want chack my answer

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  17. G

    What does the oxidation states of each element in a compound mean?

    If I have SO42-, I can figure out that the oxidation state of each O ion is 2- and the sulfur ion must then be 6+. What does this number mean? What does it tell you about the electrons in that molecule?
  18. chemisttree

    New Development in Water Oxidation

    Pretty exciting development to convert water to hydrogen and oxygen appears in http://www.sciencemag.org/cgi/content/abstract/science.1185372" ). The catalyst is based on Co4O4 stabilized with bulky polytungstate ligands. The best part is that the complex spontaneously organizes into the...
  19. E

    Why Add Sodium Dichromate Dehydrate Dropwise in Benzhydrol Oxidation?

    What is the point of adding the sodium dichromate dehydrate in water solution dropwise to benzhydrol in glacial acetic acid? Why can't we just add it all in at once? Also, what is the purpse of the glacial acetic acid?
  20. J

    Oxidation Number: Understand, Rules & Balance Redox Reactions

    I can't understand the term oxidation number.According to my textbook, it is the charge assigned to an atom. But for what purpose we are doing this?Is it for identifying the oxident and reductant in a reaction?If yes, on what basis the rules (for assigning oxidation states) are implemented...
  21. C

    What makes an oxidation state common?

    This isn't a homework question, but seemed sufficiently low-level that it belonged in this part of the forum. When one speaks of "common" oxidation states, what is meant by "common?" Is this simply to say the states most commonly occurring in nature? This would be opposed to most commonly...
  22. P

    Oxidation States of Transition Metals

    I have a question regarding the possible oxidation states of metals. I understand how to find the oxidation state of a metal in a compound, that's pretty straightforward. What I'm interested in is finding possible oxidation states given only the name of the metal. For example, Cu has possible...
  23. V

    How is development of ash and oxidation of oils in cold process soap related?

    I posted this on thedishforum: On the German soapmaking forum, there are several posts noting that there seems to be a correlation between ash and oxidation of oils. Can you speak to the presence of ash and soap going rancid? And got this reply: Yes, I could see this being an accurate...
  24. V

    Does soda ash appearing on soap mean that oxidation of oils is about to occur?

    On the German soapmaking forum, there are several posts noting that the presence of ash and the oxidation of oils(rancidity) often go together. When the ash appears in small amounts, I have not noticed any oxidation. When the ash develops over much of the surface of the soap bars, the soap...
  25. C

    Balancing Chemical Equations Using Oxidation Numbers

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  26. I

    Determining Oxidation Numbers of KClO3, NH4+, Cr2O72-, MnO42-

    Determine the oxidation numbers of the underlined elements in the following formulas:? If you could explain each one, it would be greatly appreciated. Thanks! a) KClO3 b) NH4+ c) Cr2O72- d) MnO42-
  27. P

    Oxidation of Organic Chemicals

    In the oxidation of organic chemicals, are there any conditions that must involve water or must not be in the presence of water or the oxidation process will stop despite the presence of the oxidizing agent? I remember my teacher saying something about this, but I don't remember which one it is...
  28. R

    Chemistry Calculate the oxidation no.

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  29. A

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  30. A

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  31. D

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  32. xunxine

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  33. E

    A question regarding oxidation numbers

    How come atoms have only a few oxidation numbers they can assume? For example, Cl can have the oxidation numbers -1, 1, 3, 5, 7. What prevents it from having an oxidation number of say, 2 or 4?
  34. C

    Chemical to cut headlight oxidation?

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  35. Y

    Oxidation reduction reactions

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  36. Y

    What are the oxidation numbers for each element in these compounds and ions?

    Determine the oxidation number for each atoms in the following compounds or ions: a) H3 0+ ox # -2 b)P4 O10 ox #-3 c)S8 ox #5 d)H2 CO ox #4 e)NH4 CLO4 ox #2 I need help to know if i am doing it right.
  37. Y

    Oxidation Numbers of Mn: KMnO4, LiMnO2, MnO2, K2MnCl, & Mn2O7

    determine the oxidation number for Mn in each of the following: a) KMnO4 is the ox # -3 b) LiMnO2 is the ox # +1 c) MnO2 is the ox # +2 d)K2 MnCl is the ox # +1 e)Mn2 O7 is the ox # -10 I need help ASAP PLEASE!
  38. J

    True or False: Nitrogen Family Oxidation States

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  39. M

    Does all alcohol undergo halogenation and controlled oxidation?

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  40. K

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  41. C

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  42. J

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  43. C

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  44. D

    How Does Oxidation Influence Creep in Metals?

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  45. L

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  46. J

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  47. Q

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  48. K

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  49. V

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  50. R

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