Activation energy of parallel reaction

In summary, the conversation discusses the determination of the activation energy for a parallel reaction using the Arrhenius equation. It also considers the reaction A》B and A》C and their relationship to the overall activation energy. The conversation questions the validity of a proof and acknowledges the limitations of the methods used due to factors such as temperature changes. The overall expression for the activation energy is given by e=(e1k1+e2k2)/(k1+k2).
  • #1
adi1998
15
0
Well,I know that the activation energy of a parallel reaction can be determined by the arrhenius
equation as (e1k1+e2k2)/(k1+k2) where e1,k1 and e2,k2 are the activation energies and rate constants for the two reacations.now consider the reaction A》B,and A》C since at every instant the reacted amount of A(in moles) is the sum of amounts of B and C produced,assume that in time dA moles of A react.the energy of activation required will be e1*dB+e2*dC=e*dAwhere dB and dC moles of B and C are formed and the total energy of activation being e.Using the rate law definition now yields the same result.Is this proof also valid?I understand that these are all crude approximations(temperature changes may affect the result etc)
 
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  • #2
adi1998 said:
Is this proof also valid?
Proof of what? What in particular are you trying to accomplish?
 
  • #3
I am talking about the expression for the overall activation energy
,given by e=(e1k1+e2k2)/(k1+k2).
 

1. What is activation energy of parallel reaction?

Activation energy of parallel reaction refers to the minimum amount of energy required for a chemical reaction to occur. In parallel reactions, there are multiple pathways for the reactants to form products, and each pathway has its own activation energy.

2. How is activation energy of parallel reaction determined?

The activation energy of parallel reaction can be determined experimentally by measuring the rate of reaction at different temperatures and using the Arrhenius equation. It can also be calculated theoretically using computational methods.

3. How does activation energy of parallel reaction affect the rate of reaction?

A higher activation energy means that there is a higher energy barrier for the reaction to occur, resulting in a slower rate of reaction. Conversely, a lower activation energy allows the reaction to occur more easily, leading to a faster rate of reaction.

4. Can the activation energy of parallel reaction be lowered?

Yes, the activation energy of parallel reaction can be lowered by using a catalyst. A catalyst provides an alternative pathway with a lower activation energy, making it easier for the reaction to occur and increasing the rate of reaction.

5. How does temperature affect the activation energy of parallel reaction?

Increasing the temperature of a reaction typically decreases the activation energy, as more molecules have enough energy to overcome the energy barrier and react. However, this relationship may vary depending on the specific reaction and its reactants.

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