Are All Triplet States Symmetric in Spin Wavefunction Across Different Atoms?

In summary, the triplet state in helium atom is represented by a symmetric spin wavefunction and Fermions are represented by an anti-symmetric total wavefunction, implying a greater distance between the electrons compared to a symmetric spatial wavefunction in the case of singlet state.
  • #1
Amith2006
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Homework Statement



# The triplet state in helium atom is represented by a symmetric spin wavefunction. Are all triplet states of an atom represented by a symmetric spin wavefunction or is this just in the case of helium atom?

# Fermions are represented by an anti-symmetric total wavefunction. So if a pair of electrons is in the triplet state, it will be represented by a symmetric spin wavefunction and an anti-symmetric space wavefunction because,

Total wavefunction= [tex]\psi[/tex](space) x [tex]\psi[/tex](spin)

it is said that an anti-symmetric spatial wavefunction implies a greater distance between the electrons when compared to a symmetric spatial wave function as in the case of singlet state. Could anyone please help me in understanding the whole idea behind this?

Homework Equations





The Attempt at a Solution

 
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  • #2
Amith2006 said:
It is said that an anti-symmetric spatial wavefunction implies a greater distance between the electrons when compared to a symmetric spatial wave function as in the case of singlet state. Could anyone please help me in understanding the whole idea behind this?

Try plotting the spatial wavefunctions in the two cases, or find somewhere where they are already plotted.
The anti-symmetric spatial wavefunction means that there is a exp[r1-r2] appearing in the wavefunction instead of exp[-(r1+r2)] for electron 1 and 2. The wavefunction will then have minimal probability amplitude when r1 --> r2 so the electrons' expectation values are furthest from each other.
 

Related to Are All Triplet States Symmetric in Spin Wavefunction Across Different Atoms?

What is a triplet state wavefunction?

A triplet state wavefunction is a mathematical representation of the quantum state of a system with three particles, where the total spin of the particles is equal to 1. It describes the probability amplitude of finding the particles in a certain configuration.

How is a triplet state wavefunction different from a singlet state wavefunction?

A singlet state wavefunction describes a system with two particles where the total spin is equal to 0, while a triplet state wavefunction describes a system with three particles where the total spin is equal to 1. This difference in spin results in different mathematical expressions for the wavefunctions.

What factors influence the shape of a triplet state wavefunction?

The shape of a triplet state wavefunction is influenced by the relative positions and spin orientations of the particles in the system. The spin-spin interaction between the particles can also affect the shape of the wavefunction.

How is the triplet state wavefunction used in chemistry?

In chemistry, the triplet state wavefunction is used to describe the electronic structure and properties of molecules with unpaired electrons. It is particularly important in understanding the behavior of radical species.

What techniques are used to calculate the triplet state wavefunction?

The triplet state wavefunction can be calculated using various quantum mechanical methods, such as Hartree-Fock theory, density functional theory, and configuration interaction. These methods use mathematical equations to approximate the wavefunction and solve for its values.

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