Average energy for n-state system

In summary, to find the average energy for a given state with discrete energy values, one can use the weighted sum of probabilities, where the probabilities are given by the Boltzmann distribution. In the case of a harmonic oscillator, the sum goes to infinity and can be evaluated using a common trick of taking the partial derivative and using the fact that it commutes with summation. The final result can be obtained by normalizing the expectation value.
  • #1
danyull
9
1

Homework Statement


Find the average energy ##\langle E \rangle## for
(a) an n-state system in which a given state can have energy 0, ε, 2ε, 3ε... nε.
(b) a harmonic oscillator, in which a state can have energy 0, ε, 2ε, 3ε... (i.e. with no upper limit).

Homework Equations


Definition of temperature: ##β = \frac 1 {K_BT} = \frac {d lnΩ(E)} {dE}##
Boltzmann distribution: ##P(ε) ∝ e^{-εβ}##

The Attempt at a Solution


Since the energy here takes on discrete values, the average is found by taking the weighted sum of the probabilities, $$\langle E \rangle = \sum_{n=0}^n nε~e^{-nεβ}$$
and in the case of part (b), the sum goes to infinity. My problem is I don't know how to evaluate these sums. Any help would be appreciated, thanks!
 
Physics news on Phys.org
  • #2
One commonly used trick to evaluate such sums is the following observation that
[tex]
n\varepsilon\,e^{-n\varepsilon \beta} = - \frac{\partial}{\partial \beta } (e^{-n\varepsilon \beta})
[/tex]
and use the fact that the partial derivative commutes with the summation to get
[tex]
\sum_{n=0}^{N} n\varepsilon\,e^{-n\varepsilon \beta} = - \frac{\partial}{\partial \beta } \sum_{n=0}^{N} e^{-n\varepsilon \beta}
[/tex]
The summation is now simply just a geometric series.
(and don't forget to normalize your expectation value)
 
  • Like
Likes danyull, TSny and DrClaude

What is the definition of "average energy for n-state system"?

The average energy for n-state system refers to the average amount of energy possessed by a system with n possible states. It takes into account the probability of each state and calculates the overall average energy of the system.

How is the average energy for n-state system calculated?

The average energy for n-state system is calculated by taking the sum of the product of each state's energy and its corresponding probability. This is then divided by the total number of states in the system.

What is the significance of the average energy for n-state system in thermodynamics?

In thermodynamics, the average energy for n-state system is used to determine the equilibrium state of a system. It helps in understanding the behavior and properties of a system at a macroscopic level.

Can the average energy for n-state system change?

Yes, the average energy for n-state system can change if there is a change in the energy levels of the individual states or if the probabilities of the states change. This can happen due to external factors such as temperature or pressure.

How does the concept of entropy relate to the average energy for n-state system?

Entropy is a measure of the disorder or randomness in a system. The average energy for n-state system is directly related to the entropy as it is a measure of the average energy of the system's states. An increase in the number of possible states or an increase in the energy of the states leads to an increase in entropy.

Similar threads

  • Advanced Physics Homework Help
Replies
14
Views
1K
  • Advanced Physics Homework Help
Replies
2
Views
831
  • Advanced Physics Homework Help
Replies
4
Views
1K
  • Advanced Physics Homework Help
Replies
1
Views
1K
  • Advanced Physics Homework Help
Replies
1
Views
2K
  • Advanced Physics Homework Help
Replies
1
Views
926
  • Advanced Physics Homework Help
Replies
3
Views
901
Replies
4
Views
1K
  • Advanced Physics Homework Help
Replies
1
Views
2K
Replies
1
Views
473
Back
Top