Average magnetic moment of atom in magnetic field ##B##

In summary, the conversation discusses the relationship between the average energy and the canonical partition function for one atom. The goal is to show that ##\langle \mu \rangle = \beta^{-1} (\partial \log Z / \partial B)##, where ##Z## is the canonical partition function and ##\mu = \mu_0 m##. The conversation also mentions the Feynman-Hellman theorem as a way to link the two results.
  • #1
ergospherical
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from the partition function - am trying to show that ##\langle \mu \rangle = \beta^{-1} (\partial \log Z / \partial B)## where ##Z## is the canonical partition function for one atom, i.e. ##Z = \sum_{m=-j}^{j} \mathrm{exp}(\mu_0 \beta B m)##, and ##\mu = \mu_0 m##. The average energy:\begin{align*}
\langle E \rangle = - \frac{\partial}{\partial \beta} \log Z
\end{align*}and ##\langle E \rangle = -\langle \mu \rangle B ##. How do I get the derivative ##\partial B/ \partial \beta## to link the two results? Or is there another way.
 
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  • #2
I guess you mean ##H_{\text{mag}}=-\vec{\mu}_{\text{mag}} \cdot \vec{B}## in the Hamiltonian; unfortunately ##\mu## is already reserved for the chemical potential of some charge or particle-number like conserved quantity (or quantities).

Then your formula follows from the Feynman-Hellman theorem as usual.
 

1. What is the average magnetic moment of an atom in a magnetic field?

The average magnetic moment of an atom in a magnetic field is a measure of the strength and direction of the atom's magnetic dipole moment when subjected to an external magnetic field. It is a vector quantity and is expressed in units of magnetic dipole moment per unit volume.

2. How is the average magnetic moment of an atom affected by the strength of the magnetic field?

The average magnetic moment of an atom is directly proportional to the strength of the magnetic field it is placed in. This means that as the strength of the magnetic field increases, the average magnetic moment of the atom also increases.

3. What factors can influence the average magnetic moment of an atom in a magnetic field?

The average magnetic moment of an atom can be influenced by factors such as the type of atom, its electronic configuration, and the strength and direction of the external magnetic field. Additionally, temperature and the presence of other nearby atoms can also affect the average magnetic moment.

4. How is the average magnetic moment of an atom related to its magnetic susceptibility?

The average magnetic moment of an atom is directly related to its magnetic susceptibility, which is a measure of how easily the atom can be magnetized. A higher average magnetic moment corresponds to a higher magnetic susceptibility.

5. Can the average magnetic moment of an atom be measured experimentally?

Yes, the average magnetic moment of an atom can be measured experimentally using techniques such as nuclear magnetic resonance (NMR) or electron paramagnetic resonance (EPR). These techniques involve subjecting the atom to a magnetic field and measuring the resulting magnetic response.

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