Calculating Ksp of Thallium Chloride at 100 Degrees Celsius

In summary, to calculate the Ksp of Thallium(1) Chloride at 100 degrees Celsius, you need to determine the molar concentration of Thallium and Chloride, which should be equal, based on the equation Ksp = [Tl1+][Cl1-]. The concentration of the saturated solution of salt at this temperature is 2.4g/100ml, which is equivalent to 0.677 mol/L of Cl. From there, you can calculate the molar concentration of Tl and use it to find the Ksp value.
  • #1
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I am having a tough time with getting my heard around what Ksp is; this question isbugging the heck out of me:

Q:
Calculate the Ksp of Thallium(1) Chloride at 100 Degrease celcius. The concentration of saturated solution of salt at this temperature is 2.4g / 100 ml .

Me:
As far as i got...

The Ksp of Thallium = [TI][Cl]

and

2.4 g / 100 ml is 0.677 mol / L of Cl ?


But beyond that I don't understand what i should be doing...
 
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  • #2
Ksp = [Tl1+][Cl1-], which you wrote correctly.

So what is the molar concentration of each species? Tl and Cl must have the same concentration, and one mole of TlCl, yields one mole of each species.
 
  • #3


A:

Calculating the Ksp of a compound involves determining the solubility product constant, which is a measure of how much of the compound can dissolve in water at a given temperature. In this case, we are looking at the solubility of Thallium Chloride at 100 degrees Celsius.

First, we need to write the balanced chemical equation for the dissolution of Thallium Chloride in water:

TlCl (s) --> Tl+ (aq) + Cl- (aq)

Next, we need to determine the molar solubility of Thallium Chloride at 100 degrees Celsius. This is given as 2.4g / 100 ml, which can be converted to 0.024 g / mL. Since the molar mass of TlCl is 239.84 g/mol, this means that the molar solubility is 0.0001 mol/L.

Now, we can use this molar solubility to calculate the Ksp:

Ksp = [Tl+][Cl-] = (0.0001 mol/L)(0.0001 mol/L) = 1 x 10^-8

Therefore, the Ksp of Thallium Chloride at 100 degrees Celsius is 1 x 10^-8. I hope this helps clarify the concept of Ksp for you.
 

Related to Calculating Ksp of Thallium Chloride at 100 Degrees Celsius

1. What is the chemical equation for the dissociation of thallium chloride at 100 degrees Celsius?

The chemical equation for the dissociation of thallium chloride at 100 degrees Celsius is TlCl ⇌ Tl+ + Cl-.

2. How do you calculate the molar solubility of thallium chloride at 100 degrees Celsius?

The molar solubility of thallium chloride at 100 degrees Celsius can be calculated by using the Ksp expression: Ksp = [Tl+][Cl-]. This value can then be used to calculate the molar solubility using the given molar concentration of thallium chloride.

3. What is the significance of calculating Ksp for thallium chloride at 100 degrees Celsius?

Calculating the Ksp for thallium chloride at 100 degrees Celsius allows us to determine the solubility of the compound at this specific temperature. It also provides information about the strength of the bonds between thallium and chloride ions at this temperature.

4. How does temperature affect the Ksp of thallium chloride?

Temperature has a direct effect on the Ksp of thallium chloride. As the temperature increases, the solubility of thallium chloride also increases, leading to a higher Ksp value. This is because the increased temperature provides more energy for the ions to break apart and dissolve in the solution.

5. What factors can affect the accuracy of the calculated Ksp for thallium chloride at 100 degrees Celsius?

The accuracy of the calculated Ksp for thallium chloride at 100 degrees Celsius can be affected by factors such as experimental error, impurities in the sample, and changes in temperature or pressure during the experiment. It is important to minimize these factors in order to obtain a more accurate value.

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