Differentiate between iron and copper sulphide

In summary: Ammonia is also a common household product, often used for cleaning.In summary, to determine if the black, lustrous powder is from a copper or steel pipe, you can dissolve it in hydrochloric acid and add drops of ammonia. If the color turns blue, it contains copper. If it forms a precipitate, it likely contains iron. If it doesn't dissolve easily, you may need to digest the sample with nitric acid before adding ammonia. Flame tests can also be conducted by dissolving the sample in either HCl or nitric acid and then heating it over a flame. Copper will produce a green-blue color, while iron may be difficult to see. It is important to use proper safety precautions and equipment when handling
  • #1
Jehannum
102
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TL;DR Summary
Simple chemical / flame test needed to identify substance
I have a quantity of black, lustrous powder taken from inside a gas pipe.

I want to know whether it's from copper pipe or from steel pipe.

Is there a very simple test I can do? I'm not a chemist and have no specialist equipment.
 
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  • #2
Dissolve it in HCL. To several drops of the liquid add several drops of ammonia. If it turns blue, it contains copper. If it forms a ppt, it’s iron.

If it won’t dissolve easily, it is probably an organometallic iron compound or an iron compound with organic “stuff” coating it. In that case you would need to digest the sample with nitric acid before adding the ammonia. You need special equipment and protections to handle that.
If you want to do flame tests, you need to dissolve some of it first... either with HCl or HNO3 (nitric acid). Dissolve the sample, decant or filter and heat to boil. Reduce to a moist solid and reconstitute in a minimum of DI water. Dip a q-tip into the liquid and hold over a BLUE flame to observe the color. Iron will likely be difficult to see but copper (green-blue) is easy.
 
  • #3
To amplify @chemisttree nice post:

HCl is hydrochloric acid, which you can get at hardware and pool supply stores.
 

1. What is the chemical formula for iron sulphide?

The chemical formula for iron sulphide is FeS.

2. What is the chemical formula for copper sulphide?

The chemical formula for copper sulphide is CuS.

3. How do iron and copper sulphide differ in terms of appearance?

Iron sulphide is a black or dark grey solid, while copper sulphide is a reddish-brown solid.

4. What are the main uses of iron sulphide?

Iron sulphide is commonly used in the production of iron and steel, as well as in the manufacturing of sulfuric acid and batteries.

5. What are the main uses of copper sulphide?

Copper sulphide is used in the production of copper, as well as in the manufacturing of batteries, pigments, and fungicides.

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