Does agitation make gases dissolve faster?

In summary, when soda is shaken, the agitation causes some of the CO2 to come out of solution, which is why it fizzes when opened. However, this also means that the CO2 will dissolve back into the soda when it is left to settle, creating a stable state. The shaking process simply speeds up the process of gas coming out of solution, but it can also help the gas dissolve back into the liquid if there is no excess gas present.
  • #1
ejnovek
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Why is CO2 released when soda is shaked, and dissolves again when the soda is stable?

My teacher in class today said that soluble gases will dissolve faster in the presence of agitation. In practice (e.g. shaking a bottle of soda), this seems to not be the case. Please explain

Thank You,

EJ
 
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  • #2
Not really sure ... but in could be that zones of different pressure are created in agitation. The ones with lower than "calm" pressure will ease the opposition of surface tension by bubbles. And the ones with higher should see no effect.

I assume this is what happens when you hit a beer bottle from top towards the bottom than creates the well known beer fountain. While dropping a bottle on the table does not produce a similar effect at least in intensity.
 
  • #3
The CO2 in a can of soda is kept in solution by pressure. When you open the can, this pressure is released and some of the CO2 comes out of solution and forms bubbles.

http://en.wikipedia.org/wiki/Carbonation

http://www.livescience.com/32492-why-does-soda-fizz.html

Adding energy to the soda by shaking the can or tapping on the side will cause some of the CO2 to come out of solution. If the top is opened simultaneously when a lot of the CO2 comes out of solution, then you'll get a soda fountain.
 
  • #4
Agitation can make gasses dissolve in liquids faster, but this also means that it speeds up the reverse process: gasses coming out of supersaturated solutions. As SteamKing mentioned, opening a can of soda gives a supersaturated solution of carbon dioxide. Because carbon dioxide is above its solutility limit, it will come out of solution, and shaking helps this process occur more quickly. If you were opening a can of liquid which had been de-gased (and had no dissolved carbon dioxide), shaking this solution would help atmospheric carbon dioxide dissolve in the liquid until it reached its solubility limit.
 
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  • #5


I can confirm that agitation does indeed make gases dissolve faster. This is because agitation, such as shaking a bottle of soda, increases the surface area and contact between the gas and the liquid, allowing for more gas molecules to dissolve into the liquid. However, in the case of soda, the agitation also causes the release of carbon dioxide gas.

When soda is manufactured, it is carbonated by dissolving carbon dioxide gas into the liquid. This gas is under pressure and remains dissolved in the liquid until the bottle is opened. When the bottle is shaken, the increased pressure and movement causes the gas to escape from the liquid, resulting in the familiar fizzing and release of bubbles.

Once the soda is stable again, the agitation has stopped and the pressure has decreased, allowing the carbon dioxide gas to re-dissolve into the liquid. This is why the soda appears to have "lost its fizz" after being shaken, but regains it after being left to sit for a while.

In summary, agitation can indeed make gases dissolve faster, but in the case of soda, it also causes the release of the gas. The gas will then re-dissolve when the agitation stops and the pressure decreases. This is a common phenomenon in carbonated beverages and can be explained by the principles of gas solubility and pressure.
 

1. Does agitation affect gas solubility?

Yes, agitation can affect the solubility of gases in a liquid. When a liquid is agitated, it creates turbulence and increases the contact between the gas and the liquid, allowing for more gas molecules to dissolve into the liquid.

2. How does agitation impact gas solubility?

Agitation increases the kinetic energy of the gas molecules, causing them to collide with the liquid molecules more frequently and with greater force. This increases the chances of the gas molecules being absorbed into the liquid, resulting in a faster rate of gas dissolution.

3. Is agitation necessary for gas to dissolve in a liquid?

No, agitation is not always necessary for gas to dissolve in a liquid. Some gases, such as carbon dioxide, are highly soluble in water and can dissolve without agitation. However, agitation can significantly speed up the process of gas dissolution.

4. Can agitation cause gases to dissolve beyond their maximum solubility?

Yes, agitation can cause gases to dissolve beyond their maximum solubility. This is because the increased turbulence and contact between the gas and the liquid can overcome the forces that prevent the gas from dissolving, such as the gas pressure and the liquid's surface tension.

5. Does temperature affect the impact of agitation on gas solubility?

Yes, temperature can affect the impact of agitation on gas solubility. Generally, as temperature increases, the kinetic energy of the gas molecules also increases, making them more likely to dissolve in the liquid even without agitation. However, agitation can still have a significant impact on gas solubility at higher temperatures by increasing the surface area of the liquid and creating more opportunities for gas-liquid interactions.

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