Electrochemical Cells - oxidants and reductants

In summary, the conversation discusses an electrochemical cell involving copper and magnesium, where copper is the oxidant and gains electrons while magnesium loses electrons. The difference in reactivity between the two electrodes encourages magnesium to lose electrons, as seen in the standard electrode potential tables. This is due to the energy levels and solvation properties of magnesium. Additionally, the presence of two valency electrons in magnesium makes it more prone to giving off its electrons compared to copper with only one valency electron.
  • #1
Da Apprentice
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In an electrochemical cell involving copper and magnesium copper gains electrons (is the oxidant) and Magnesium the opposite. I understand that Cu is the least reactive of the two electodes and therefore the Mg gives up electrons to stop the Cu from oxidising, but why does this difference in reactivity encourage the Mg to lose electrons? and also why is cu considered the least reastive of the two electrodes? Cu has only one valency electrode where as Mg has two so therefore shouldn't it require less energy to exchange Coppers one electron than magnesiums two?

Thanks,
 
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  • #2
You haven't quite got it right in a few places.
First:
Cu2+ is normally what you get not Cu+.
Second:
First look at the two processes independently:
Mg <-> Mg2+ + 2 e-
Cu <-> Cu 2+ + 2 e-
For detailed reasons about energy levels and solvation Mg is more prone to give off its electrons. This can be looked up in standard electrode potential tables. If you then connect the two systems with a wire the extra electrons from the Mg electrode will flow towards the copper electrode.Did that help?
 

1. What is an electrochemical cell?

An electrochemical cell is a device that converts chemical energy into electrical energy or vice versa. It consists of two electrodes, an anode and a cathode, which are immersed in an electrolyte solution. The chemical reactions that take place at the electrodes produce an electric current.

2. What is the role of oxidants and reductants in electrochemical cells?

Oxidants and reductants are the key components of electrochemical cells. Oxidants are substances that accept electrons from the anode, while reductants are substances that donate electrons to the cathode. These reactions at the electrodes drive the flow of electrons and generate an electric current.

3. What is the difference between an oxidant and a reductant?

An oxidant is a substance that oxidizes or removes electrons from another substance, while a reductant is a substance that reduces or adds electrons to another substance. In an electrochemical cell, the oxidant and reductant work together to facilitate the flow of electrons and produce electrical energy.

4. What are some common examples of oxidants and reductants?

Some common examples of oxidants include oxygen, chlorine, and hydrogen peroxide. Examples of reductants include hydrogen, carbon monoxide, and iron. In electrochemical cells, metals such as zinc and copper are often used as reductants, while non-metals like fluorine and chlorine can act as oxidants.

5. How are electrochemical cells used in everyday life?

Electrochemical cells have a wide range of applications in our daily lives. Some common uses include batteries for portable electronic devices, fuel cells for powering vehicles, and corrosion prevention in metal structures. They are also used in various industrial processes, such as wastewater treatment and metal refining.

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