Fermi-Dirac statistics, finding all electron configurations

In summary, the conversation discusses the process of determining the possible configurations of a system with 20 electrons and equidistant energy levels. It is revealed that there are only 24 possible configurations, which can be found through counting or by sorting them in a systematic manner. It is noted that a computer can quickly perform this task, but there may be other methods that are faster.
  • #1
sigint00
2
0
Hello everyone. I'm having trouble understanding this example: https://ecee.colorado.edu/~bart/book/book/chapter2/ch2_5.htm#2_5_2

In this system of 20 electrons with equidistant energy levels, how is it known that there are only 24 possible configurations, and how are those configurations found?
 
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  • #2
By counting. You can set up fancy sums, but ultimately it is just a matter of counting.
If you want a systematic approach, sort them by energy of the highest occupied level for example, then by occupancy of that level, then by energy of the second highest occupied level, ...
Alternatively sort by number of excited electrons.
 
  • #3
mfb said:
By counting. You can set up fancy sums, but ultimately it is just a matter of counting.
If you want a systematic approach, sort them by energy of the highest occupied level for example, then by occupancy of that level, then by energy of the second highest occupied level, ...
Alternatively sort by number of excited electrons.

So there's no getting around this just being a long process of trial-and-error? or I'm misunderstanding, maybe...
 
  • #4
24 states, it is not that long, and a computer does it in less than a millisecond.
I'm not aware of a method that is faster than counting the states, but that doesn't mean there can't be such a method.
 

1. What is Fermi-Dirac statistics?

Fermi-Dirac statistics is a branch of quantum statistics that describes the behavior of particles with half-integer spin, such as electrons. It is used to calculate the probability of finding a particle in a specific energy state at a given temperature.

2. How is Fermi-Dirac statistics different from other statistical models?

Fermi-Dirac statistics takes into account the Pauli exclusion principle, which states that no two particles can occupy the same quantum state simultaneously. This makes it more suitable for describing the behavior of fermions, such as electrons, which obey this principle.

3. How do you calculate all possible electron configurations using Fermi-Dirac statistics?

To calculate all possible electron configurations, you need to first determine the number of electrons in the system and the number of available energy states. Then, using the Fermi-Dirac distribution function, you can calculate the probability of each energy state being occupied by an electron. Finally, you can use this information to construct all possible electron configurations.

4. What is the significance of finding all electron configurations?

Finding all electron configurations is important in understanding the electronic structure of atoms and molecules. It allows us to determine the stability and reactivity of these systems, as well as predict their chemical and physical properties.

5. Can Fermi-Dirac statistics be applied to other particles besides electrons?

Yes, Fermi-Dirac statistics can be applied to any type of fermion, such as protons, neutrons, and quarks. It can also be extended to describe the behavior of composite particles, such as atoms and molecules, which are made up of multiple fermions.

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