Finding the number of free electrons

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In summary, the concentration of free electrons per cubic meter of a metal is given by the equation n = d*v/AM = A0dv*10^3/A, where d is the density, v is the valence (number of free electrons per atom), A is the atomic weight, M is the weight of an atom of unit atomic weight, and A0 is Avogadro's number. This can also be expressed as N = d/(AM) or N = d*A0*10^3/A, where N is the number of atoms of A amu in d kg. This intermediate weight of amu is used because A0 is the number of atoms of 1 amu in 1 gram, making it
  • #1
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Homework Statement
Prove that the concentration n of free electrons per cubic meter of a metal is given by
n = d*v/AM = A0dv*10^3/A
where d = density, kg/m^3
v = valence, free electrons per atom
A = atomic weight
M = weight of atom of unit atomic weight, kg
A0 = Avogadro's number, molecules/mole
Relevant Equations
1gram = A*1amu
The required number of free electrons to be calculated is
##n = \frac{dv} {AM} = \frac{A_0dv*10^3} {A} ##
I know mass of single atom is ##M##
The atomic weight of mole of atoms is ##A##.
Hence ##A = A_0*M ##
##d = \frac{A} {1} ## -> "1" represents ##1m^3##. I am confused how to proceed further. How do i approach?
 
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  • #2
PhysicsTest said:
Homework Statement:: Prove that the concentration n of free electrons per cubic meter of a metal is given by
n = d*v/AM = A0dv*10^3/A
where d = density, kg/m^3
v = valence, free electrons per atom
A = atomic weight
M = weight of atom of unit atomic weight, kg
A0 = Avogadro's number, molecules/mole
Relevant Equations:: 1gram = A*1amu

The required number of free electrons to be calculated is
##n = \frac{dv} {AM} = \frac{A_0dv*10^3} {A} ##
I know mass of single atom is ##M##
The atomic weight of mole of atoms is ##A##.
Hence ##A = A_0*M ##
##d = \frac{A} {1} ## -> "1" represents ##1m^3##. I am confused how to proceed further. How do i approach?
If you have the density (in ##kg/m^3##), then you need to calculate now many atoms are in a cubic metre. That means how many atoms there are in a ##kg##. Can you calculate that?

Or, alternatively, what is the mass of an atom in ##kg##?
 
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  • #3
PhysicsTest said:
Relevant Equations:: 1gram = A*1amu
This should be ##1g = A_0 \times 1 amu##.

That means that ##A_0## things of mass ##1 amu## have a mass of ##1g##.
 
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  • #4
After some struggle, this is how i approached
PeroK said:
Or, alternatively, what is the mass of an atom in ##kg##?
Mass of an atom in kg is ##\frac{A*10^{-3}} {A_0} kg## ----> eq1
If the number of atoms in ##1m^3## of volume is ##n##.
Then the mass of the total atoms is ##\frac{nA*10^{-3}} {A_0}## ----> eq2
##density = \frac{mass} {volume};## volume = ##1m^3##
##d = \frac{nA*10^{-3}} {1* A_0}## ----> eq3
Hence the number of atoms
##n =\frac{dA_0*10^3} {A} ## ---> eq4.
If there are ##v## valence electrons for each atom then the concentration of free electrons is
##n =\frac{dvA_0*10^3} {A}## ---> eq5
 
  • #5
Okay, that's the answer, but it looks complicated and you've used ##n## as the number of atoms and the number of valence electrons. Let's use ##N## for the number of atoms per cubic metre and ##m## for the mass of a single atom.

First, we know, by definition, that $$m = A \ amu$$ And we also know that $$M \ kg = 1 \ amu$$ because you are told that an atom if ##1 \ amu## has a mass of ##M \ kg##. This gives us the mass of an atom in ##kg##: $$m = AM \ kg$$ The number of atoms in ##d \ kg## is: $$N = \frac{d}{AM}$$
Alternatively, we know by definition that:

##A_0## is the number of atoms of ##1 \ amu## in ##1g##

and ##A_0 \times 10^3## is the number of atoms of ##1 \ amu## in one ##kg##,

hence ##\frac{ A_0 \times 10^3}{A}## is the number of atoms of ##A \ amu## in one ##kg##,

and ##N = \frac{d \ A_0 \times 10^3}{A}## is the number of atoms of ##A \ amu## in ##d \ kg##
 
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  • #6
Thank you for the help, the solution now looks more in order. but it is confusing ##1 \text{ amu}, A\text{ amu} ## etc. They could have started directly defining in terms of ## grams ## of the weight of the atom. Why they defined an intermediate weight of ##amu##?
 

Related to Finding the number of free electrons

1. How do you find the number of free electrons in a substance?

The number of free electrons in a substance can be found by using the equation n = N/V, where n is the number of free electrons, N is the total number of atoms in the substance, and V is the volume of the substance.

2. What is the unit of measurement for the number of free electrons?

The unit of measurement for the number of free electrons is typically expressed in per cubic meter (m-3) or per cubic centimeter (cm-3).

3. How does temperature affect the number of free electrons in a substance?

As temperature increases, the number of free electrons in a substance also increases. This is because at higher temperatures, more atoms are ionized, resulting in more free electrons.

4. Can the number of free electrons be negative?

No, the number of free electrons cannot be negative. It is a measure of the excess or deficit of electrons in a substance compared to its neutral state.

5. What is the significance of knowing the number of free electrons in a substance?

Knowing the number of free electrons in a substance is important in understanding its electrical conductivity and other properties. It also helps in designing and optimizing electronic devices and materials for specific purposes.

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