Hard soft acid base theory, i'm not understanding it

In summary, according to the HSAB theory, the equilibrium for the given reaction lies towards the products due to the formation of a hard acid and hard base in the products.
  • #1
lil_angel_007
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Homework Statement



the question asks to determine if the equilibrium is greater, equal or less than 1. one of the equation is the following:
[CuI4]2- (aq) + [CuCl4]3- (aq) ↔ [CuCl4]2-(aq) + [CuI4]3- (aq)


Homework Equations





The Attempt at a Solution



the solution given was:
the answer using the HSAB theory is:
HA-SB + SA-HB <-> HA-HB + SA-SB
(respectively) so equilibrium lies towards the products. I don't know how they labeled some of these elements:
i understand that in the first product Copper with an oxidation state of 2+ is a hard acid, Iodine is a soft base with oxidation state of 1-. In the second product, copper is a soft acid with an oxidation state of 1+ (am i right) and Cl is a soft base. Then in the products: i see copper is a hard acid with an oxidation state of 2+ but why is Cl a hard base? in the second product copper is a soft acid (ox state of 1+) and I is a soft base..

basically my question is why is the chloride ion a hard base in the second product?
 
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  • #2
The answer using the HSAB theory is: HA-SB + SA-HB <-> HA-HB + SA-SB (respectively) so equilibrium lies towards the products. Copper with an oxidation state of 2+ is a hard acid, Iodine is a soft base with oxidation state of 1-. Copper is a soft acid with an oxidation state of 1+ and Chloride is a hard base. The chloride ion is a hard base in the second product because it is more electronegative than Iodine, making it more likely to accept electrons from the copper ion. This makes the reaction favour the products, as the hard acid and hard base are forming the product, and the soft acid and soft base are forming the reactant.
 

1. What is the Hard Soft Acid Base (HSAB) theory?

The HSAB theory is a concept in chemistry that explains the behavior and reactivity of acids and bases based on their relative strengths and softness or hardness. It suggests that hard acids prefer to bond with hard bases, while soft acids prefer to bond with soft bases.

2. What is the difference between hard and soft acids and bases?

Hard acids and bases are characterized by having smaller, highly charged ions with high electronegativity, while soft acids and bases have larger, less charged ions with low electronegativity. Hard acids and bases tend to form strong, ionic bonds, while soft acids and bases tend to form weaker, covalent bonds.

3. How does the HSAB theory explain the stability of chemical compounds?

The HSAB theory suggests that hard acids and bases prefer to bond with each other due to their similar properties, resulting in more stable compounds. On the other hand, soft acids and bases prefer to bond with each other, which can lead to less stable compounds.

4. Can the HSAB theory be applied to all chemical reactions?

No, the HSAB theory is a general concept that can be applied to many chemical reactions, but it is not applicable to all reactions. Some reactions may involve a combination of hard and soft acids and bases, making it more complicated to predict the behavior of the compounds.

5. How is the HSAB theory useful in practical applications?

The HSAB theory is useful in predicting the stability and reactivity of chemical compounds, which has practical applications in fields such as pharmaceuticals, materials science, and catalysis. It can also be used to explain the selectivity of certain reactions and aid in the design of new compounds with desired properties.

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