Intermolecular Bonding of CH4: Van der Waals

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In summary, the conversation discusses the type of intermolecular bonding that occurs in gaseous CH4. The correct answer is option D, van der Waals forces, because CH4 is a non-polar molecule and does not participate in hydrogen bonding. This type of bonding is different from covalent and ionic bonds, which are considered intramolecular forces. Van der Waals forces are a combination of Keyson, Debye, and London forces.
  • #1
brake4country
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Homework Statement


What type of intermolecular bonding occurs in gaseous CH4?
(A) covalent
(B) ionic
(C) hydrogen
(D) van der Waals


Homework Equations





The Attempt at a Solution



Here is what I did: ruled out B (not ionic) and chose A. The correct answer is D. Is C wrong because hydrogen bonding only happens between polar molecules? Why is D correct over A? Is it because covalent = intramolecular, not intermolecular? Thanks in advance.
 
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  • #2
Physically a covalent bond involves sharing electrons.
The image is that electron orbit both whatsits concerned.
This requires the whatsits to get very close to each other: the range is of order of an Angstrom.

Do individual CH4 molecule share electrons with each other?
 
  • #3
The C shares electrons with the hydrogens to complete their shells. This answer should be covalent.
 
  • #4
Does the C share it's electrons with H atoms in other molecules?
 
  • #5
No it doesn't. It's a non-polar molecule. In researching, I learned that hydrogen bonding is not applicable here because CH4 is not polar. Therefore, the "intramolecular" forces are covalent, but that's not what the question is asking. The question asks "intermolecular" forces which exist between atoms. Ionic, covalent, and hydrogen bonding our out; leaving van der waals forces.

I think I get it now. If I am missing something, please share! Thanks!
 
  • #6
That's right - the question was basically about whether you understood the difference between inter and intra molecular forces. Covalent and Ionic bonds are intra-molecular: they are what holds molecules together.

There is a good summary:
http://www.chem.ufl.edu/~itl/4411/lectures/lec_g.html
... Van-der Waals forces are the sum of Keyson, Debye, and London forces.
 
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1. What is Van der Waals force?

Van der Waals force is a type of intermolecular force that occurs between molecules. It is a weak force that arises due to temporary dipoles in molecules, which attract each other. This force is responsible for the attraction between non-polar molecules, such as in the case of CH4.

2. How does Van der Waals force affect the properties of CH4?

Van der Waals force affects the properties of CH4 by increasing its boiling point and melting point. This is because the force of attraction between molecules is stronger, making it more difficult for the molecules to separate from each other. Additionally, Van der Waals force contributes to the overall stability of the molecule.

3. How is Van der Waals force different from other types of intermolecular forces?

Van der Waals force is different from other types of intermolecular forces because it is a weak force that is only present in non-polar molecules. Other intermolecular forces, such as hydrogen bonding and dipole-dipole interactions, are stronger and are found in polar molecules.

4. Can Van der Waals force be broken?

Yes, Van der Waals force can be broken. This force is relatively weak, so it can be overcome by other stronger forces, such as ionic or covalent bonds. Additionally, changes in temperature and pressure can also affect the strength of Van der Waals force.

5. How does the size of molecules affect Van der Waals force?

The size of molecules can affect Van der Waals force because larger molecules have a larger surface area, which allows for more points of contact between molecules. This leads to a stronger Van der Waals force between the molecules. Conversely, smaller molecules have a smaller surface area and therefore, a weaker Van der Waals force.

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