Interstitial position probability?

In summary, the question asks for the probability of a Ni atom being placed in an interstitial configuration at 320 C, given the formation energies for substitutional and interstitial Ni atoms. Using the equation for the number of vacancies, the probabilities for both types of configurations can be calculated. The probability for an interstitial Ni atom is higher than that for a substitutional Ni atom, with a value of 0.323 compared to 0.033.
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Homework Statement


A silicon crystal is being doped with Ni atoms. The formation energies for substitutional and interstitial Ni atoms are Es= 0.74 eV and Ei=0.16 eV, respectively. At 320 centigrade, what is the probability for a Ni atom to be placed in an interstitial configurations?

Homework Equations


## \frac{n_v}{N} = e^{-\frac{Q}{RT}} ##

The Attempt at a Solution


I started this problem by calculating the number of vacancies for the substitutional and interstitial energy at 320 C. However, I am not so sure where to go from there. Would would I use this equation to get a probability?
 
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  • #2
Do I need to use a different equation? Es = 0.74 eVEi = 0.16 eVT = 320 C## n_v = N * e^{-\frac{Es}{RT}} #### n_v = N * e^{-\frac{Ei}{RT}} #### n_v(substitutional) = N * e^{-\frac{0.74eV}{8.617*10^{-5}eV/K * 593K}} = N * 0.033 #### n_v(interstitial) = N * e^{-\frac{0.16eV}{8.617*10^{-5}eV/K * 593K}} = N * 0.323 ##
 

What is interstitial position probability?

Interstitial position probability is a term used in statistical mechanics to describe the likelihood of finding a particle or atom in the empty space between other particles or atoms in a given system. It is often used to study the behavior of gases, liquids, and solids at the atomic level.

What factors affect interstitial position probability?

The interstitial position probability is influenced by several factors including the temperature, pressure, and composition of the system. It is also affected by the size and shape of the particles or atoms in the system, as well as any external forces acting on the system.

How is interstitial position probability calculated?

The calculation of interstitial position probability involves using statistical methods such as the Boltzmann distribution to determine the probability of a particle or atom occupying a specific interstitial position. This calculation can also take into account the interactions between particles or atoms in the system.

Why is interstitial position probability important?

Understanding interstitial position probability is crucial in explaining the properties and behaviors of materials at the atomic level. It is also important in industries such as material science, where the arrangement of atoms can greatly impact the properties of a material.

How can interstitial position probability be experimentally determined?

There are several experimental techniques that can be used to determine interstitial position probability, including X-ray diffraction, neutron scattering, and electron microscopy. These methods allow scientists to directly observe the arrangement of atoms in a material and calculate the probability of finding atoms in interstitial positions.

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