L-Idose (configuration, chirality and stereocenters)?

In summary, L-Idose is a monosaccharide molecule with six carbon atoms and five hydroxyl groups. It exists in a cyclic form with a five-membered ring and has a chiral center at carbon 2, making it optically active. The configuration of L-Idose is D-aldose, meaning that the hydroxyl group on the highest numbered chiral carbon is on the left side in the Fischer projection. It also has two additional stereocenters at carbon 3 and 4, resulting in four possible stereoisomers. L-Idose is an important component of various biological molecules, including glycolipids and glycoproteins, and plays a crucial role in cellular signaling
  • #1
GeeR_3
I'm struggling with the following problem:
  1. Draw (using Haworth notation) the L-Idose
  2. Is it chiral?
  3. Nominate every functional group
  4. Mark every stereocenter
Now, I tried doing the following, but I'm quite frankly confused: which one Idose is the correct (meaning the true L-) one?

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1. What is the configuration of L-Idose?

The configuration of L-Idose is L, which indicates that the molecule has a left-handed orientation around the chiral center.

2. How many stereocenters does L-Idose have?

L-Idose has 4 stereocenters, which are carbon atoms with four different groups attached to them, making them optically active.

3. What is the chirality of L-Idose?

L-Idose is a chiral molecule, meaning it cannot be superimposed on its mirror image. This is due to the presence of stereocenters, which give the molecule a non-superimposable 3D shape.

4. Can L-Idose exist as both D and L enantiomers?

No, L-Idose can only exist as the L enantiomer due to its specific arrangement of atoms around the chiral centers. D-Idose would have a different configuration and would not be considered the same molecule.

5. How is the configuration of L-Idose determined?

The configuration of L-Idose is determined by the arrangement of groups around the chiral center, following the Cahn-Ingold-Prelog priority rules. The highest priority group is placed in the back, and the remaining groups are arranged in a counterclockwise direction to determine the L configuration.

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