- #1
Silviu
- 624
- 11
Hello! I have a question about the first problem in Stat Mech (Physical Adsorption) from http://web.mit.edu/physics/current/graduate/exams/gen2_F01.pdf. The solution to it can be found http://web.mit.edu/physics/current/graduate/exams/gen2sol_F01.pdf. I understand the logic they use for the solution, but I am not sure I understand why do they use the partition function of the canonical ensemble and not the grand canonical one. If I understand the problem well, the particles can go from the wall of the container to the inside of the container and the other way around, so the number of particles in not fixed (but the average is). Also, there is no way to exchange energy here, other than particles moving from wall to the inside of the container. So why don't we use the GC ensemble partition function (i.e. adding the term ##e^{-\mu N/KT}##)? Thank you!