Solve Fick's second law of diffusion

In summary, the conversation discusses how to solve Fick's second law of diffusion with specific conditions and the obtained solution is c(x,t)=A erfc(\frac{x}{2\sqrt{Dt}}). The method used to arrive at this solution is the Laplace method for PDE resolution, specifically using a single Laplace transform. Another suggestion is to use a similarity solution or refer to the book "Transport Phenomena" for a similar problem.
  • #1
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I'm curious how to solve Fick's second law of diffusion [tex]\frac{∂c}{∂t}=D \frac{∂^2c}{∂x^2}[/tex]For conditions:[tex]c(x,0)=0[/tex][tex]c(0,t)=A[/tex][tex]c(\infty,t)=0[/tex]Physically this means:
-c(x,t) is the concentration at point x at time t.
-Initially there is no concentration of diffusing species.
-At x=0 for all t the is a constant concentration "a".
-As x goes to infinity for all time, the concentration is 0.
-D is the diffusivity, assume it is a constant.

The solution is:[tex]c(x,t)=A erfc(\frac{x}{2\sqrt{Dt}})[/tex]
What method was used to arrive at that solution?
 
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  • #2
Hi !

May be this formula was obtained thanks to the Laplace method for PDE resolution.
Normally we would have to use the double Laplace transform (relatively to x AND t), which would be rather arduous.
But the PDE and boundary conditions are simple enough to use the usual single Laplace transform (relatively to t only).
 

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  • #3
Possibly try a similarity solution?
 
  • #4
Transport Phenomena by Bird, Stewart, and Lightfoot show how to solve this (singular perturbation boundary layer problem) using similarity solutions. Look for the analogous viscous flow startup problem.
 
  • #5


The solution to Fick's second law of diffusion can be found using separation of variables and the method of eigenfunction expansion. This involves assuming a solution of the form c(x,t) = X(x)T(t) and substituting it into the equation. This leads to separating the equation into two ordinary differential equations, one for X(x) and one for T(t). From there, boundary conditions can be applied to solve for the coefficients and obtain the final solution. In this case, the boundary conditions at x=0 and x=\infty were used to solve for the constant A and the error function, erfc, was used to represent the concentration profile over time.
 

What is Fick's second law of diffusion?

Fick's second law of diffusion is a mathematical equation that describes the rate at which a substance diffuses through a medium. It is often used in studies of heat transfer or mass transfer, and is named after German physicist Adolf Fick.

What is the equation for Fick's second law of diffusion?

The equation for Fick's second law of diffusion is dC/dt = D(d^2C/dx^2), where C is the concentration of the diffusing substance, t is time, D is the diffusion coefficient, and x is the distance along the diffusion path.

How is Fick's second law of diffusion different from Fick's first law?

Fick's first law only applies to cases where the concentration gradient is constant, while Fick's second law takes into account changes in concentration over time and distance. Additionally, Fick's first law only applies to diffusion in one dimension, while Fick's second law can be used for diffusion in multiple dimensions.

What are the units of the diffusion coefficient (D) in Fick's second law of diffusion?

The units of the diffusion coefficient (D) in Fick's second law of diffusion depend on the units of concentration and distance used in the equation. For example, if concentration is measured in moles per cubic meter and distance in meters, then the units of D would be m^2/s.

What are some applications of Fick's second law of diffusion?

Fick's second law of diffusion has many practical applications, such as predicting the movement of pollutants in the environment, designing drug delivery systems in medicine, and understanding the diffusion of gases in industrial processes. It is also used in fields such as materials science, chemical engineering, and geology.

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